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【资源】Advances in Friedel-Crafts Acylation Reactions: Catalytic and Green Proc
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书籍名称: Advances in Friedel-Crafts Acylation Reactions: Catalytic and Green Processes 大小: 4MB 书籍类别: 催化化学/ 多相催化 / CRC / 英文版 书籍作者: Giovanni Sartori, Raimondo Mag 书籍等级: 书籍格式: pdf(editorial) ，出版年代：2009 发布日期: 2010年03月13日15:53 , 审核日期: 2010年03月13日15:57 Advances in Friedel-Crafts Acylation Reactions: Catalytic and Green Processes By Giovanni Sartori, Raimondo Maggi * Publisher: CRC Press * Number Of Pages: 216 * Publication Date: 2009-12-04 * ISBN-10 / ASIN: 1420067923 * ISBN-13 / EAN: 9781420067927 Product Description: Used in the production of a wide number of fine chemicals and pharmaceuticals, the Friedel-Crafts acylation reaction represents a synthetic process of great interest to organic chemists of academia and industry. Nearly 40 years since the last major treatise on the topic and reflecting the growing emphasis on green technology, Advances in Friedel-Crafts Acylation Reactions: Catalytic and Green Processes focuses on how to make this reaction more economically and environmentally friendly by using green acylating conditions, thus minimizing the formation of waste and decreasing production costs. Divided into four parts, the book explores stoichiometric acylations, catalytic homogeneous acylations, catalytic heterogeneous acylations, and phenol acylations. It is structured according to the role played by the catalyst in the activation of reagents as well as in the different modes of regioselectivity encountered in the acylation of arenes, aromatic ethers, and phenols. Incorporating examples of all acid-catalyzed Friedel-Crafts acylation reactions, the text considers classic Lewis and Brönsted acid types along with more innovative and advanced multicomponent superacid catalysts. These range from rare earth triflates or triflimides and their combination with ionic liquids to metal-promoted zeolites and zeotypes, clays, polymetal oxides, sulfated zirconia, heteropoly acids, and Nafion. The book emphasizes the major industrial applications, providing a critical assessment of the differences, advantages, and disadvantages of homogeneous and heterogeneous catalysis. Helping readers to better understand the mechanism of the Friedel-Crafts acylation, the examples in the book substantiate the development of more effective catalysts and more selective processes achieved during the last few decades, enabling industry to embark on a safer and more efficient synthesis of aromatic ketones for the manufacture of a wide array of products. http://s31.ifile.it/dhewjg4/sjfr ... 23%20AcylationA.rar 更多国内链接见chemj论坛 http://www.chemj.cn/plugin.php?i ... iew&softid=2112 希望大家支持、见谅 |
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