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Title: Electrostatic Self-Assembly of a Pt-around-Au Nanocomposite with High Activity towards Formic Acid Oxidation

Author:Sheng Zhang, Yuyan Shao, Geping Yin and Yuehe Lin

Address:Address:
1 School of Chemical Engineering & Technology, Harbin Institute of Technology                  
2 Pacific Northwest National Laboratory, Richland, WA

Abstract: A Pt-around-Au nanocomposite is synthesized by electrostatic self-assembly (see picture; PDDA=poly(diallyldimethylammonium chloride)). This catalyst shows significantly improved activity towards formic acid oxidation versus pure Pt catalysts. The possible reason is the efficient spillover of HCOO from Au to the surrounding Pt nanoparticles, where HCOO is further oxidized to CO2.

Llink:www3.interscience.wiley.com/journal/123300959/abstract


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Decision£ºWe are pleased to inform you that the above-mentioned manuscript has been accepted for publication in ANGEWANDTE CHEMIE. However, we request that you revise your manuscript taking into consideration the enclosed comments from 2 of our referee(s). It would be helpful if you were to prepare the final version of the manuscript in accordance with the checklist in the attached file. Of particular importance is the presentation of the graphical material: if it can be reproduced directly, the possibility of errors is reduced and your correction of the author proofs facilitated.

Æäʵ¿ªÊ¼Éè¼ÆÊµÑéµÄÄ¿µÄÊÇ£º ÓÃAuÀ´ÐÞÊÎPt nanoparticles£¬Ìá¸ßPtµÄÎȶ¨ÐÔ£¬µ«Êǽá¹û²»ÀíÏë¡£½áºÏ×Ô¼ºÒÔǰµÄÎÄÕ£¨S. Zhang, Y. Y. Shao, G. P. Yin and Y. H. Lin, J. Power Sources, 2010, 195, 1103.£©£¬³öºõÒâÁϵط¢ÏÖ£¬ÐÂÖÆ±¸µÄPt-around-Au¶Ô¼×Ëá¾ßÓм«¸ßµÄ´ß»¯»îÐÔ¡£È»ºó£¬²¹³äÁËTEM ºÍXRDÎïÀí±íÕ÷£¬ËÑË÷ÁËÏà¹ØÎÄÏ×£¬×¼±¸Ð´ÎÄÕ¡£µ«ÊǺÍYuYan Shao £¨±¾ÈËʦÐÖ£©ÌÖÂۺ󣬾õµÃÒÔǰµÄÀíÂÛ²¢²»ÄܽâÊÍÏÖÔÚµÄÏÖÏó¡£ÓÚÊǽøÐÐÁËCOÎü¸½ÊÔÑ飬¾Ý´ËÌá³öÁ˼×ËáÑõ»¯µÄлúÀí¡£ÎÄÕÂдºÃºó£¬ÐÞ¸ÄÁËÎåÁùƪ£¬Í¶³öºóÖ±½Ó½ÓÊÕ¡£ÕâÊÇÎÒÃÇ×éÀïµÄµÚһƪ¸ßµµ´ÎµÄÎÄÕ£¬²¢ÇÒÊÇVIP paper.  Your communication is a Very Important Paper (VIP) according to the evaluation of two referees. Less than 5% of our manuscripts receive such a positive recommendation. As a service for our authors and readers we announce forthcoming VIPs as early as possible in the journal (authors and title only; see box in the table of contents) and on our homepage (authors, title, abstract). We recommend that you tell the publicity/press department of your institute about your publication and the excellent reviews that it has received; a press release could be possible. You are welcome to submit a cover picture suggestion; VIPs are favored when we make a selection process.


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