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xiaofu119

木虫 (著名写手)

[交流] 【讨论】ZnO光催化

有没有做ZnO光催化的啊?讨论一下吧
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buffaloli

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★ ★ ★
xiaofu119(金币+1):谢谢参与
nxl5096224(金币+2):3Q~ 1-24 19:18
最新的ZnO系列空心球光催化-ACS Nano

http://pubs.acs.org/cgi-bin/arti ... html/nn800353q.html


ABSTRACT A weak acid selective etching strategy was put forward to fabricate oxide-based hollow
nanoparticles (HNPs) using core/shell nanostructures of active metal/oxide nanoparticles as sacrificial templates.
ZnO-based HNPs, including pure ZnO, Au/ZnO, Pt/ZnO, and Au/Pt/ZnO HNPs with diameter below 50 nm and shell
thickness below 6 nm has been first achieved at low temperature. The diameter, thickness, and even sizes of ZnO
and noble metal ultrafine crystals of HNPs can be well adjusted by the etching process. Synchronous with the
formation of HNPs, the internal metalsemiconductor interfaces can be controllably eliminated (ZnZnO) and
reconstructed (noble metalZnO). Excitingly, such microstructure manipulation has endued them with giant
improvements in related performances, including the very strong blue luminescence with enhancement over 3
orders of magnitude for the pure ZnO HNPs and the greatly improved photocatalytic activity for the noble metal/
ZnO HNPs. These give them strong potentials in relevant applications, such as blue light emitting devices,
environment remediation, drug delivery and release, energy storage and conversion, and sensors. The designed
fabrication procedure is simple, feasible, and universal for a series of oxide and noble metal/oxide HNPs with
controlled microstructure and improved performances.
11楼2010-01-23 07:20:52
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yongxa

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小木虫(金币+0.5):给个红包,谢谢回帖交流
相对于二氧化钛来说,做氧化锌光催化的就少了
3楼2010-01-20 09:22:13
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xiaofu119

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我做的ZnO在前30min还可以,后来怎么就没动静了呢,是催化性能不稳定吗?是不是一般都要高温退火哦!
4楼2010-01-20 09:27:18
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xiaofu119

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引用回帖:
Originally posted by threestone819 at 2010-1-20 15:02:
ZnO没有TiO2稳定

你做过这两样中的一个吗?
6楼2010-01-20 16:26:17
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