| ²é¿´: 360 | »Ø¸´: 7 | |||
| µ±Ç°Ö÷ÌâÒѾ´æµµ¡£ | |||
| µ±Ç°Ö»ÏÔʾÂú×ãÖ¸¶¨Ìõ¼þµÄ»ØÌû£¬µã»÷ÕâÀï²é¿´±¾»°ÌâµÄËùÓлØÌû | |||
yjhdrгæ (³õÈëÎÄ̳)
|
[½»Á÷]
ÇóÖúÖÐÒëÓ¢Ò»¾äºÍÓ¢ÒëÖÐ3С¶Î£¨½ØÖ¹ÓÚ2009ÄêÔªÔÂ9ÈÕ22£º00ǰ£©
|
||
|
ÇóÖúÖÐÒëÓ¢Ò»¾äºÍÓ¢ÒëÖÐ3С¶Î£¨½ØÖ¹ÓÚ2009ÄêÔªÔÂ9ÈÕ22£º00ǰ£©¡£ л¾øÈí¼þ·Ò룡£¡£¡¡£ 1. £¨ÖÐÒëÓ¢£©¸ßµ¯ÐԵĵª»¯ÅðÄÉÃ׹ܣ¨»·£©¸´ºÏ²ÄÁϽṹÉè¼Æ¼°ÆäʵÑéÑо¿ 2. £¨Ó¢ÒëÖУ© Carbon nanotubes (CNTs) are a new type of carbon material with very broad prospects because of to their unique structure and excellent physical and chemical properties.¡¾1-4¡¿ In particular, their excellent mechanical properties have aroused widespread interest in the scientific community, and some progress has been made in applying them to toughen materials.¡¾5-13¡¿ The structure of boron nitride nanotubes (BNNTs) is very similar to that of carbon nanotubes. Their B and N atoms have shown hybridized orbitals and form hexagonal planar net structures like graphite. Each B or N atom allows a electron to develop a conjugated bond, where two running electronics on the plane are stemmed from each BN unit. As a result, BNNTs have structures that are similar to CNTs and exhibit many similar physical and chemical properties. In terms of different BNNTs layers, they can also be divided into single-walled tubes and multi-walled tube structures. In particular, BNNTs are made up of atoms of boron and nitrogen that are more oxidation resistant and are expected to have better mechanical and electronic properties than their well-known cousins, carbon nanotubes. Far more resistant to oxidation than CNTs, BNNTs are suited to high-temperature applications in which carbon nanostructures would burn.¡¾14¡¿ They are expected to be semiconducting, with predictable electronic properties independent of tube diameter and number of layers, unlike tubes made of carbon.¡¾15¡¿ Compared with CNTs, BNNTs have shown great advantage in improving mechanical properties at high temperature, thermal stability, oxidation resistance, and so on. Super composite materials prepared with BNNTs, such as superstrength composite materials and great conductive ceramic composite materials, can be subjected to high temperature and other harsh environmental variables, and can be widely used in metallurgical, chemical, aerospace, machinery and other fields. Studies of the electronic structure of BNNTs have been carried out,¡¾16-21¡¿ but reports of their mechanical properties have been few. The compression characteristics of (5, 5) SWBNNTs were studied by Moon and Hwang.¡¾22¡¿ Shen compared the tensile and compressive properties of BN nanotubes and nanopeapods.¡¾23¡¿ In a recent research study, Griebel, Hamaekers and Heber examined the Young¡¯s modulus of (6,m) boron nitride nanotubes with vacancy and functionalization defects.¡¾24¡¿ Similar to the situation when studying CNT composites, to obtain BNNT composites with better mechanical properties, it is necessary to discover an effective form of chemical treatment that achieves the best graft of the functional group in terms of variety, quantity, and location. We have already reported the effects of grafted carboxyl and amine on the elastic properties of single-walled carbon nanotubes (SWCNTs).¡¾25,26¡¿ Based on these works, we further investigate the effects of grafted carboxyl on the elastic moduli of armchair and zigzag SWBNNTs. The results show that the grafting has a greater impact on zigzag SWBNNTs, and the grafted zigzag SWBNNTs have more stable elastic moduli when more grafts are applied. The opposite occurs with the armchair SWBNNTs: there is a smaller grafting effect and greater fluctuations in the moduli as the graft quantity increases. The reasons for this difference are analyzed in terms of the isoline structure of the deformation electron density and bond-length variation of the grafted BNNTs. |
» ²ÂÄãϲ»¶
Çóµ÷¼Á
ÒѾÓÐ3È˻ظ´
Ò»Ö¾Ô¸±±¾©»¯¹¤´óѧ£¬³õÊԳɼ¨350Çóµ÷¼Á
ÒѾÓÐ14È˻ظ´
¸´ÊÔµ÷¼Á
ÒѾÓÐ4È˻ظ´
323·Ö£¨¼ÆËã»úÊÓ¾õºÍ´óÄ£ÐÍÏîÄ¿£©ÄÜÖ±½ÓÉÏÊÖ
ÒѾÓÐ3È˻ظ´
311·Ö 22408 Çóµ÷¼Á
ÒѾÓÐ3È˻ظ´
320·ÖÈ˹¤ÖÇÄܵ÷¼Á
ÒѾÓÐ7È˻ظ´
Ò»Ö¾Ô¸Ö£´ó0705Çóµ÷¼Á
ÒѾÓÐ4È˻ظ´
0703»¯Ñ§
ÒѾÓÐ10È˻ظ´
301Çóµ÷¼Á
ÒѾÓÐ10È˻ظ´
306·Ö²ÄÁÏÓ뻯¹¤Çóµ÷¼Á
ÒѾÓÐ6È˻ظ´
cam967
½ð³æ (ÖøÃûдÊÖ)
- ·ÒëEPI: 21
- Ó¦Öú: 0 (Ó×¶ùÔ°)
- ½ð±Ò: 1146.8
- É¢½ð: 330
- ºì»¨: 2
- Ìû×Ó: 1082
- ÔÚÏß: 268.7Сʱ
- ³æºÅ: 549628
- ×¢²á: 2008-04-21
- ÐÔ±ð: GG
- רҵ: ¸ß·Ö×Ó£¬ÄÉÃ×£¬ÉúÎï
¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï
zap65535(½ð±Ò+10,VIP+0):2010ÔÙ½ÓÔÙÀ÷£¬Äã¶®µÃ¡£ 1-9 22:10
zap65535(½ð±Ò+10,VIP+0):2010ÔÙ½ÓÔÙÀ÷£¬Äã¶®µÃ¡£ 1-9 22:10
|
ÄöµØ·½²»Ì«¾«È·£¿ |
8Â¥2010-01-09 21:53:39
cam967
½ð³æ (ÖøÃûдÊÖ)
- ·ÒëEPI: 21
- Ó¦Öú: 0 (Ó×¶ùÔ°)
- ½ð±Ò: 1146.8
- É¢½ð: 330
- ºì»¨: 2
- Ìû×Ó: 1082
- ÔÚÏß: 268.7Сʱ
- ³æºÅ: 549628
- ×¢²á: 2008-04-21
- ÐÔ±ð: GG
- רҵ: ¸ß·Ö×Ó£¬ÄÉÃ×£¬ÉúÎï
¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï
yjhdr(½ð±Ò+30,VIP+0):ºÃ£¡ 1-9 13:43
yjhdr(½ð±Ò+30,VIP+0):ºÃ£¡ 1-9 13:43
|
1. £¨ÖÐÒëÓ¢£©¸ßµ¯ÐԵĵª»¯ÅðÄÉÃ׹ܣ¨»·£©¸´ºÏ²ÄÁϽṹÉè¼Æ¼°ÆäʵÑéÑо¿ Structure Design and Experimental research of BNNTs £¨nanopeapod?£©with High Elasticity 2. £¨Ó¢ÒëÖУ© ̼ÄÉÃ×¹ÜÓÉÓÚ¾ßÓжÀÌØµÄ½á¹¹ºÍÓÅÒìµÄÎïÀí»¯Ñ§ÐÔÄÜ£¬ÒѾ³ÉΪһÖÖÓÐ׏ãÀ«Ó¦ÓÃǰ¾°µÄвÄÁÏ¡£ËûÃÇÓÅÒìµÄ»úеÐÔÄÜÓÈÆäÊܵ½¿ÆÑ§½çµÄÖØÊÓ£¬¶øÇÒÔÚÔöÈͲÄÁÏ·½ÃæÈ¡µÃÁËÒ»¶¨½øÕ¹¡£BNNTs½á¹¹Óë̼ÄÉÃ׹ܺÜÏàËÆ¡£ÓÉÓÚN,BÔ×ÓÖ®¼ä¹ìµÀÔÓ»¯£¬ÐγÉÁ˺Íʯīϩ½á¹¹ºÜÏàËÆµÄÁù½ÇÍø×´Æ½Ãæ½á¹¹¡£Ã¿¸öN,BÔ×Ó¶¼ÓÃ×îÍâ²ãµÄÒ»¸öµç×ÓÓÃÓÚ¹¹½¨¹²éî¼ü£¬ÓÚÊÇ£¬Ã¿¸öN,Bµ¥Î»¾ÍÄÜÌṩÁ½¸ö×ÔÓɵç×Ó¡£Òò´Ë£¬BNNTsµÄ½á¹¹ÓëCNTºÞÏàËÆ£¬²¢¾ß±¸Ðí¶àÓÅÒìÐÔÄÜ¡£¸ù¾ÝBNNTs²ãÊýµÄ²»Í¬£¬Ò²¿É·ÖΪµ¥±ÚºÍ¶à±Ú¹Ü½á¹¹¡£ÌرðÖµµÃÒ»ÌáµÄÊÇ£¬ÓÉÓÚN,BµÄ±ÈC¿¹Ñõ»¯ÐÔÄܸüºÃ£¬Òò´Ë£¬¿ÆÑ§¼ÒÔ¤²âBNNTsµÄ»úеÐÔÄܺ͵çѧÐÔÄÜ»á±ÈCNT¸üºÃ¡£ÒòΪBNNTÊÇ¿¹Ñõ»¯ÐÔ¸üÇ¿£¬ËùÒÔ¿ÉÓÃÓÚ¸ßγ¡ºÏ£¬¶øÔÚÏàͬÌõ¼þÏÂCNTÔò»áȼÉÕ¡£¶øÇÒ£¬ËüÃǶ¼Êǰ뵼ÌåÐԵ쬵çѧÐÔÄÜ¿ÉÒÔÉè¼Æ²¢ÇÒ²»ÏñCNTÒ»ÑùÓë¹Ü×ÓÖ±¾¶ºÍ²ãÊýÓйء£ ºÍCNTÏà±È£¬BNNTsµÄ¸ßÎÂÏ»úеÐÔÄÜ£¬ÈÈÎȶ¨ÐÔ£¬¿¹Ñõ»¯ÐԵȶ¼¸üºÃ¡£ ÓÉBNNTÖÆ±¸µÄ³¬¸´ºÏ²ÄÁÏ£¨È糬ǿ¸´ºÏ²ÄÁϺͳ¬µ¼Ìմɸ´ºÏ²ÄÁÏ£© £¬¿ÉÒÔÔÚ¸ßÎÂÒÔ¼°ÆäËû¿Á¿ÌÌõ¼þÏÂʹÓ㬲¢ÇÒÔÚÒ±½ð£¬»¯Ñ§£¬ÓîÖæ£¬»úеµÈ·½ÃæÓÐ׏㷺µÄÓ¦ÓÃǰ¾°¡£ ÒÑÓб¨µÀÑо¿ÁËBNNTµÄµç×ӽṹ£¬µ«¶ÔÆä»úеÐÔÄܵÄÑо¿±¨µÀ²»¶à¡£MoonµÈÑо¿ÁË55SWBNNTµÄѹËõÌØÐÔ£¬ShenµÈÑо¿ÁËBNNTºÍBNNPµÄÀÉìºÍѹËõÐÔÄÜ.×î½üµÄÒ»Ôò±¨µÀÖУ¬GriedbeµÈÑо¿ÁË£¨6£¬m£©BNNTÒýÈ빦ÄÜ»¯È±ÏÝǰºóµÄÑîÊÏÄ£Á¿£¨vacancyÊǿհ׵ÄÒâ˼£¬ÐèÒª²ÎÕÕÔÎÄ£¬¹À¼Æ·µÃ²»×¼È·£© ºÍÑо¿CNT¸´ºÏ²ÄÁÏÏàËÆ£¬ÎªÁËʹBNNT¸´ºÏ²ÄÁÏ»úеÐÔÄܸüºÃ£¬ºÜÓбØÒªÑ°ÕÒÒ»ÖÖÓÐЧµÄ»¯Ñ§·½·¨Ê¹¹ÙÄÜÍÅÔÚBNNTÉϽÓÖ¦µÄÖÖÀ࣬ÊýÁ¿£¬Î»Öôﵽ×î¼Ñ¡£ÎÒÃÇÒѾÑо¿ÁËôÈ»ùºÍ°±»ù¶ÔSWNTµ¯ÐÔµÄÓ°Ï죬ÔÚ´Ë»ù´¡ÉÏ£¬ÎÒÃǽøÒ»²½Ñо¿Á˽ÓÖ¦ôÈ»ù¶Ô·öÊÖÒÎÐͺ;â³ÝÐÎSWBNNµ¯ÐÔÄ£Á¿µÄÓ°Ï졣ʵÑé½á¹û±íÃ÷£º½ÓÖ¦¶Ô¾â³ÝÐÎSWBNNÓ°Ïì¸ü´ó£¬¶øÇÒµ±½ÓÖ¦ÃܶÈÔö´óʱ£¬ËüµÄµ¯ÐÔÄ£Á¿Îȶ¨ÐÔÔö¼Ó£»¶ø·öÊÖÒÎÐ͵ÄÔòÓë´ËÏà·´£º½ÓÖ¦¶ÔÆäÓ°Ïì¸üС£¬¶øÇÒËæ×ŽÓÖ¦ÃÜ¶È¼Ó´ó£¬Æäµ¯ÐÔÄ£Á¿Îȶ¨ÐÔ½µµÍ¡£ÎªÁ˽âÊͲúÉúÕâ¸ö²»Í¬µÄÔÒò£¬´ÓÐαäµç×ÓÃܶȵÈÖµÏߣ¨Ã»¼û¹ý£¬²»ÖªµÀÊÇɶ²ÎÊý£©ºÍ½ÓÖ¦¼ü³¤±ä»¯½øÐÐÁË·ÖÎö¡£ |
2Â¥2010-01-08 23:29:42
cam967
½ð³æ (ÖøÃûдÊÖ)
- ·ÒëEPI: 21
- Ó¦Öú: 0 (Ó×¶ùÔ°)
- ½ð±Ò: 1146.8
- É¢½ð: 330
- ºì»¨: 2
- Ìû×Ó: 1082
- ÔÚÏß: 268.7Сʱ
- ³æºÅ: 549628
- ×¢²á: 2008-04-21
- ÐÔ±ð: GG
- רҵ: ¸ß·Ö×Ó£¬ÄÉÃ×£¬ÉúÎï
3Â¥2010-01-08 23:35:37
zap65535
ľ³æ (ÖøÃûдÊÖ)
Á½Ôº´óѧʿºó
- ·ÒëEPI: 9
- Ó¦Öú: 2 (Ó×¶ùÔ°)
- ¹ó±ö: 0.711
- ½ð±Ò: 1507.7
- É¢½ð: 887
- ºì»¨: 2
- Ìû×Ó: 1820
- ÔÚÏß: 157.1Сʱ
- ³æºÅ: 704450
- ×¢²á: 2009-02-19
- ÐÔ±ð: GG
- רҵ: Âí¿Ë˼Ö÷Òå˼ÏëÊ·
4Â¥2010-01-09 08:29:04














»Ø¸´´ËÂ¥
