|
|
★
小木虫(金币+0.5):给个红包，谢谢回帖交流
SciFinder了下，R=CH3时就这一篇
Hydrogenation of furan compounds over platinum and rhodium catalysts. Shuikin, N. I.; Bel'skii, I. F. Inst. Org. Chem., Acad. Sci., Moscow, Zhurnal Obshchei Khimii (1959), 29 1093-6. CODEN: ZOKHA4 ISSN: 0044-460X. Journal language unavailable. CAN 54:7147 AN 1960:7147 CAPLUS
Abstract
cf. Ibid. 442. Hydrogenation of sylvan over Pt-C at 150 gave 26% tetrahydrosylvan, 59% 2-pentanone, and 15% 2-pentanol. Over Rh-C at 200 it formed 40% tetrahydrosylvan and 60% 2-pentanone, while at 300 100% 2-pentanone was formed. 2-Vinylfuran over Rh-C at 150 gave 90% 2-ethylfuran. 2-Propenylfuran over Pt-C at 150 gave 90% 2-propylfuran. |
|
回复此楼