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zyp2886

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有机催化合成

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[交流] 文献信息不全,才在奖问答版求助

请虫友们帮我找几篇文献啊！大大有赏！

专利：USSR 438244(1975)

文献两篇：Beitr Plasmapnys 1975,15(4)
Can. J.Chem 1979,57(15)

文献上面就是这么写，本人也不是太懂，还希望高手能指教一下！

不清楚的可以加本人QQ 309547833 在线等，谢谢！

[ Last edited by xjxlovelxl on 2009-12-29 at 23:55 ]

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zyp2886(金币+5): 2010-02-27 18:14

专利文献：
Para-terphenyl prepn - by pyrolysis of phenol vapour in an inert gas
专利号: ~SU438244-A
专利权人和代码:SIB ORG CHEM AS(ASIO-Soviet Institute)
Derwent 主入藏号: 1975-55105W [20]
摘要: To increase the yield, p-terphenyl is prepd. by pyrolysis of phenol vapour in a quartz tube at 750 degrees C in a stream of an inert gas. The title cpd. is used in the prodn. of fluorescent and luminescent compsns. and photoemulsions, in the mfr. of thermoactive soluble polyphenylenes and as an intermediate in organic synthesis. The pyrolysis gives p-terphenyl as the main prod. (53% yield) with benzene, water, CO, H, CO2, CH4 and carbonaceous residue as by-prodts. Thus, 35.0g (0.37 mole) phenol was brought to the boil in an evaporator and the vapour was passed through a quartz tube reactor at 750 degrees C in nitrogen at 3-5 l/hr. Unreacted phenol and by-prods. were condensed and recycled into the evaporator. The reaction was continued for 5 hrs. Vacuum distn. of the prodt. gave 2.1g. phenol and 9.0g. (53% w.r.t. phenol) p-terphenyl. The by-prodt. gases contained (%) CO 41.1, H2 5.2, CO2 26.3, and CH4 12.5.

应该就是这篇了