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Advanced Carbon Electrode Materials for Molecular Electrochemistry Richard L. McCreery ¶ÔÄãÓÐÓñðÍüÁ˸ø¸öÆÀ¼ÛŶ ![]() ![]() http://d.namipan.com/d/981061c0b ... 566a5e4248bcdfe3c00 1. Introduction and Scope 2646 2. Materials Chemistry of Carbon Electrodes 2647 2.1. Carbon Allotropes 2647 2.1.1. Graphite and Related sp2 Hybridized Carbon Materials 2647 2.1.2. Diamond 2648 2.1.3. Carbon Nanotubes 2649 2.2. Electronic Properties of Carbon Electrode Materials 2649 2.3. Spectroscopy and Optical Properties 2650 3. Electrochemical Properties of Carbon Materials 2653 3.1. Surface Structure of Carbon Electrode Materials 2654 3.1.1. Termination 2654 3.1.2. Surface Oxides 2655 3.2. Electronic Structure and Conductivity 2656 3.3. Adsorption 2658 3.4. Electrocatalysis 2658 3.5. Classes of Redox Systems on Carbon Electrodes 2660 3.5.1. Outer-Sphere Redox Systems 2660 3.5.2. ¡°Surface-Sensitive¡± and Electrocatalytic Redox Systems 2661 3.6.1. Polishing and Cleaning 2663 3.6.2. Vacuum and Heat Treatments 2664 3.6.3. Carbon Electrode Activation 2665 3.7. Summary and Generalizations 2666 4. Advanced Carbon Electrode Materials 2666 4.1. Microfabricated Carbon Thin Films 2666 4.2. Boron-Doped Diamond for Electrochemistry 2668 4.3. Fibers and Nanotubes 2669 4.4. Carbon Composite Electrodes 2674 5. Carbon Surface Modification 2675 5.1. Diazonium Ion Reduction 2675 5.2. Thermal and Photochemical Modifications 2679 5.3. Amine and Carboxylate Oxidation 2680 5.4. Modification by ¡°Click¡± Chemistry 2681 6. Synopsis and Outlook 2681 7. Acknowledgments 2682 8. References 2682 [ Last edited by hls4518 on 2009-11-30 at 12:54 ] |
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