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keven7928

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[资源] 【资源】聚合物的前沿：Helical Polymers【已搜索无重复】

The helix is the central structural motif in biological
macromolecules, such as DNA and proteins, and is also the
ubiquitous object in nature from microscopic to macroscopic
points of view. Most importantly, the helical conformation is
inherently chiral, and right- and left-handed helices are exactly
mirror images of each other; therefore, they cannot be superimposed.
Accordingly, if one of the helices could be selectively
synthesized, induced, or constructed for molecules, supramolecules,
oligomers, or polymers, they should be optically active
without any additional configurationally chiral components.
Inspired by sophisticated biological helices that are of key
importance for their elaborate functions in living systems
involving molecular recognition, replication, and catalytic
activity, chemists have been challenged to develop artificial
helical polymers, supramolecules, and oligomers with a controlled
handedness, not only to mimic biological helices and
functions but also for their potential applications in materials
science, such as ferroelectric liquid crystals (LCs) and nonlinear
optical materials, sensing specific molecules, the separation of
enantiomers, and asymmetric catalysis.
本综述从合成，结构到功能都有详细的介绍，希望对高分子专业的有帮助。免费下载，别忘了评价哦！！！
http://d.namipan.com/d/7300471d4 ... da0ddc615a729c96600
http://http://d.namipan.com/d/7300471d4230de74f29e2157fbb3dda0ddc615a729c96600

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