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【有奖交流】积极回复本帖子，参与交流，就有机会分得作者 LLLSUSTech 的 24 个金币，回帖就立即获得 1 个金币，每人有 1 次机会

LLLSUSTech

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应助: 0 (幼儿园)
金币: 4208.9
帖子: 739
在线: 51.8小时
虫号: 20889265

[交流] 南科大金属/元素有机化学25级博士招生

课题组聚焦在主族元素化学。主族元素化学是介于无机化学和有机化学边界的基础科学研究方向，涉及周期表s区和p区元素。我们将以经典教科书为出发点，通过合理的设计，挑战一切“不可能”存在的分子以及从未被挖掘的成键模式，并且对其空前的化学反应活性进行系统研究。

  如果你对各种“古怪”分子的电子结构、非传统化学键的组成、前线轨道分析或者分子级别无机/有机反应机理有兴趣；如果你想挑战自己的合成水平（对极端水、氧含量控制）亦或者想从理论深度更清晰的认识化学；可以联系课题组长：刘柳（liuleoliu@sustech.edu.cn）。

课题组网页：https://faculty.sustech.edu.cn/?tagid=liuleoliu&go=2

要求：
1. 化学及相关专业的硕士毕业生或即将毕业；本硕均985（或硕士在中科院所）
2. 勤奋、踏实，具有团队协作精神；

待遇：
10万元/年奖学金。

课题组已取得成果：
22) C. Hu; X.-F. Wang; J. Li; X.-Y. Chang and L. L. Liu,* A Stable Rhodium-Coordinated Carbene with a σ0π2 Electronic Configuration, Science 2024, 383, 81–85.

21) X.-F. Wang; C. Hu; J. Li; R. Wei; X. Zhang and L. L. Liu,* A Crystalline Stannyne, Nat. Chem. 2024, 16, 1673–1679.

20) R. Wei; X.-F. Wang; C. Hu and L. L. Liu,* Synthesis and Reactivity of Copper Carbyne Anion Complexes, Nat. Synth. 2023, 2, 357–363.

19) C. Hu;+ X.-F. Wang;+ R. Wei; C. Hu; D. A. Ruiz; X.-Y. Chang and L. L. Liu,* Crystalline Monometal-Substituted Free Carbenes, Chem 2022, 8, 2278–2289. (+ = equal contribution)

18) X. Lan; H. Wang; Q. Liang* and L. L. Liu,* A Crystalline Mesoionic Diazasilole Featuring Low-Valent Silicon, Angew. Chem. Int. Ed. 2025, 64, e202415246. (Highlighted by ChemistryViews)

17) J. Li; X.-F. Wang; C. Hu and L. L. Liu,* Carbene-Stabilized Phosphagermylenylidene: A Heavier Analog of Isonitrile, J. Am. Chem. Soc. 2024, 146, 14341–14348. (Highlighted by ChemistryViews)

16) Y. Mei; X. Chen; R. Wei; X.-Y. Chang; L. Tao and L. L. Liu,* An Isolable Radical Anion Featuring a 2-Center-3-Electron π-Bond without a Clearly Defined σ-Bond, Angew. Chem. Int. Ed. 2023, 62, e202315555.

15) X. Zhang and L. L. Liu,* Crystalline Neutral Aluminum Selenide/Telluride: Isoelectronic Aluminum Analogues of Carbonyls, J. Am. Chem. Soc. 2023, 145, 15729–15734.

14) R. Wei; X.-F. Wang; D. A. Ruiz and L. L. Liu,* Stable Ketenyl Anions via Ligand Exchange at an Anionic Carbon as Powerful Synthons, Angew. Chem. Int. Ed.  2023, 62, e202219211. (Hot Paper)

13) X. Zhang; H. Wang; X. Lan; Y. Mei; D. A. Ruiz and L. L. Liu,* Transfer of an Aluminum Atom: An Avenue to Aluminum Heterocycles, CCS Chem. 2023, 5, 2059–2068. (Highlighted by CCS News)

12) J. Li; Z. Lu and L. L. Liu,* A Free Phosphaborene Stable at Room Temperature, J. Am. Chem. Soc. 2022, 144, 23691–23697. (Highlighted by ChemistryViews)

11)  R. Wei; S. Ju and L. L. Liu,* Free Metallophosphines: Extremely Electron-Rich Phosphorus Superbases that are Electronically and Sterically Tunable, Angew. Chem. Int. Ed.  2022, 61, e202205618. (Hot Paper) (Highlighted by ChemistryViews)

10) X. Zhang and L. L. Liu,* Modulating the Frontier Orbitals of an Aluminylene for Facile Dearomatization of Inert Arenes, Angew. Chem. Int. Ed. 2022, 61, e202116658. (Very Important Paper)

9) Y. Mei; Z. Yan and L. L. Liu,* Facile Synthesis of the Dicyanophosphide Anion via Electrochemical Activation of White Phosphorus: An Avenue to Organophosphorus Compounds, J. Am. Chem. Soc. 2022, 144, 1517–1522.

8) X. Zhang and L. L. Liu,* A Free Aluminylene with Diverse σ-Donating and Doubly σ/π-Accepting Ligand Features for Transition Metals, Angew. Chem. Int. Ed. 2021, 60, 27062–27069. (Hot Paper)

7) S. Li; C. Hu; L. L. Liu* and L. Wu,* Selective Hydroboration of C−C Single Bonds without Transition-Metal Catalysis, Angew. Chem. Int. Ed. 2024, 63, e202412368.

6) R. Guo;+ C. Hu;+ Q. Li; L. L. Liu;* C.-H. Tung and L. Kong,* BN Analogue of Butadiyne: A Platform for Dinitrogen Release and Reduction, J. Am. Chem. Soc. 2023,  145, 18767–18772. (+ equal contribution) (Highlighted by ChemistryViews)

5) J. Zhang; R. Wei; C. Ren; L. L. Liu* and L. Wu,* Si−B Functional Group Exchange Reaction Enabled by a Catalytic Amount of BH3: Scope, Mechanism, and Application, J. Am. Chem. Soc. 2023, 145, 15619–15629.

4) S. Qiu; X. Zhang; C. Hu; H. Chu; Q. Li; D. A. Ruiz; L. L. Liu;* C.-H. Tung and L. Kong,* Unveiling Hetero-Enyne Reactivity of Aryliminoboranes: Dearomative Hetero-Diels-Alder-Like Reactions, Angew. Chem. Int. Ed. 2022, 61, e202205814. (Hot Paper)

3) Y. Wang; X. Zhang; T. Li; Q. Li; R. Wei; D. A. Ruiz; L. L. Liu;* C.-H. Tung and L. Kong,* Crystalline Neutral Diboron Analogues of Cyclopropanes, Angew. Chem. Int. Ed. 2022, 61, e202117053. (Hot Paper) (Highlighted by ChemistryViews)

2) S. Li; C. Hu; X. Cui; J. Zhang; L. L. Liu* and L. Wu,* Site-Fixed Hydroboration of Terminal and Internal Alkenes Using BX3/iPr2NEt, Angew. Chem. Int. Ed. 2021, 60, 26238–26245.

1) R. Guo; T. Li; R. Wei; X. Zhang; Q. Li; L. L. Liu;* C. Tung and L. Kong,* Boraiminolithium: An Iminoborane-Transfer Reagent, J. Am. Chem. Soc. 2021, 143, 13483–13488. (Highlighted by ChemistryViews)

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