[求助] 丙烯酸酯的热引发本体聚合-无法有效成型问题 已有1人参与

按照文献所述的方法 采用丙烯酸丁酯为单体，引发剂AIBN，引发剂用量0.5-2%，充分溶解 将混合溶液注入自制的玻璃模具中密封，在温度60-70 ℃下反应，并不能发生完全聚合，得不到文献所述的块体聚合物 请问是什么原因 Ref. A Mechanically Robust, Self-Healing, and Adhesive Biomimetic Camouflage Ionic Conductor for Aquatic Environments “PILEs were synthesized through the polymerization of [ATAC][TFSI] and BA. Taking PILE-1 as an example, 1.752 g of [ATAC][TFSI] (equivalent to 4.0 mmol), 1.536 g of BA (equivalent to 12.0 mmol), and 0.033 g of thermal initiator AIBN were mixed and stirred. Subsequently, the mixed solution was injected into a glass mold and polymerized at 60 °C for 20 h to produce the PILE.”

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