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storm8306ľ³æ (ÕýʽдÊÖ)
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Âé·³¸ßÊÖ°ïæÐÞ¸ÄÒ»ÏÂÏÂÃæÈý¶ÎÎÄ×Ö£¬Ö÷ÒªÊÇÓï·¨ºÍ¾ä×ÓµÄÁ¬¹áÐÔ£¬Ð¡µÜÔÚ´ËÏÈл¹ýÁË¡£ ¿É×·¼Ó½ð±Ò ![]() 1wt% surfactant solutions with different amount of calcium chloride were prepared and then those tubes were put in water bath at 60¡æ for 24h. In the end, centrifugation was at 3000r/min for 1h with prespecified amount of solution, and then observes whether to have new phase to appear. The maximum amount of calcium chloride with which no new phase separates out was taken as standard that evaluates the calcium-tolerant stability of surfactant. ½«º¬Óв»Í¬Á¿ÂÈ»¯¸ÆµÄ±íÃæ»îÐÔ¼ÁÈÜÒºÔÚ60¶Èˮԡ·ÅÖÃ24Ïûʧ£¬È»ºóÀëÐĹ۲ìÊÇ·ñÓÐÐÂÏàÎö³ö£¬ÒÔ²»Îö³öÐÂÏàµÄ×î´óÂÈ»¯¸ÆÁ¿×÷ΪºâÁ¿±íÃæ»îÐÔ¼ÁÄ͸ÆÎȶ¨ÐԵıê×¼¡£ It may be due to the formation of an ¡°electronegative cavity¡± at the same time when colloid aggregation was formed [10]. As a result that calcium ions were wrapped in the inside of ¡°electronegative cavity¡± and the electronegative interface of colloid didn¡¯t change, so the colloid¡¯s inverse structures and then formation of the deposition were avoided [11]. With the increasing of length of hydrophobic chain, the cmc of CnE3SO3 decreases, the micelle aggregation number increases, the number and size of ¡°electronegative cavity¡± also increase, the capability for calcium-tolerant has a relevant increasing. Õâ¿ÉÄÜÊÇÓÉÓÚÔÚ½ºÊøÐγɵÄͬʱÐγÉÁËÒ»¸ö¸ºµç¿ÕѨ£¬¸ÆÀë×Ó±»°ü¹üÔÚ¸ºµç¿ÕѨÄÚ£¬¶ø½ºÊø±íÃæµçºÉ²»·¢Éú¸Ä±ä£¬´Ó¶ø±ÜÃâÁ˽ºÊø½á¹¹·´×ªÐγɳÁµí¡£Ëæ×ÅÊèË®Á¬µÄÔö³¤£¬ËûµÄCMC½µµÍ£¬½ºÊø¾Û¼¯ÊýÔö´ó£¬¸ºµç¿ÕѨµÄÊýÄ¿ºÍ´óС¶¼ÓÐËùÔö¼Ó£¬Òò´ËÄ͸ÆÎȶ¨ÐÔÒ²ÓÐÒ»¸öÏàÓ¦µÄÔö¼Ó¡£ An addition of strong electrolyte can accelerate surfactants¡¯ transfer from water phase to oil phase, with the result that the diffusion rate of ionic surfactant from the inner of solution to the interface rise, the electric double layer was compressed, surfactant molecules rank much more tightly, as a result that causes the emulsion stability to strengthen. However, with the further increase in salinity, the thinner the diffuse electric double layer was compressed, the more the possibility of flocculation-coalescence was, and then the more instable the emulsion was. Ç¿µç½âÖʵļÓÈë¼ÓËÙÁ˱íÃæ»îÐÔ¼Á´ÓË®ÏàÏòÓÍÏàµÄ×ªÒÆ£¬µ¼ÖÂÀë×Ó±í»î¼ÁÀ©É¢ËÙÂʵÄÔö´ó£¬Ë«µæ²ã±»Ñ¹Ëõ£¬±í»î¼ÁµÄÅÅÁиü¼Ó½ôÃÜ£¬Òò´ËÈé×´ÒºµÄÎȶ¨ÐԵõ½¼ÓÇ¿¡£µ«ÊÇËæ×ÅÑζȵĽøÒ»²½Ôö´ó£¬Ë«µæ²ã±»Ñ¹ËõµÄÔ½À´Ô½±¡£¬·¢ÉúÐõÄý¾Û¼¯µÄ¿ÉÄÜÐÔÔ½À´Ô½´ó£¬Èé×´ÒºÒ²¾Í±äµÃÔ½À´Ô½²»Îȶ¨¡£ [ Last edited by storm8306 on 2009-10-10 at 14:04 ] |
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mcphone
ͳæ (СÓÐÃûÆø)
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¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï
storm8306(½ð±Ò+15,VIP+0):лл£¬µ«ÎÒÏëÎÊһϵÚÒ»¶ÎÄÇÑùûÓÐÖ÷Óï¿ÉÐÐÂ𣿠10-10 17:40
storm8306(½ð±Ò+15,VIP+0):лл£¬µ«ÎÒÏëÎÊһϵÚÒ»¶ÎÄÇÑùûÓÐÖ÷Óï¿ÉÐÐÂ𣿠10-10 17:40
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Ó¦¸Ã×¢Òâ¾ä×ÓµÄÖ÷ÓïÑ¡Ôñ¡£ºÜ¶à¾ä×ÓÊÇûÓÐÓï·¨´íÎ󣬵«Ç°ºóҪͳһÊéдÈ˳ơ£ÉÙÁ¿´ÊÓï´îÅä´íÓï Prepare 1wt% surfactant solutions with different amount of calcium chloride and allow to keep in in water bath at 60¡æ for 24h.Obtain prespecified amount of solution after centrifugation at 3000r/min for 1h, and then observe the filtrate whether new phase appears. The maximum amount of calcium chloride with which no new phase separates out was considered as evaluation standard of the calcium-tolerant stability of surfactant. It may be due to the formation of an ¡°electronegative cavity¡± at the same time when colloid aggregation was formed [10]. calcium ions were wrapped in the inside of ¡°electronegative cavity¡± and the electronegative interface of colloid didn¡¯t change, so tha the colloid¡¯s inverse structures and formation of the deposition were avoided [11]. With the increasing of length of hydrophobic chain, the cmc of CnE3SO3 decreased, the micelle aggregation number as well as the number and size of ¡°electronegative cavity¡± also increased, and therefor the calcium-tolerant stability was improved to some degree. surfactants were accelerated to transfer from water phase to oil phase with An addition of strong electrolyte so that the diffusion rate of ionic surfactant from the inner of solution to the interface increased, , the electric double layer was compressed, surfactant molecules were arranged much more tightly,and finally the emulsion stability could be improved. However, with the further increase in salinity, the thinner the diffuse electric double layer was compressed, the more the possibility of flocculation-coalescence was, and then the more instable the emulsion was. |
2Â¥2009-10-10 16:08:15
in order to observe whether there were any new phases precipitating out,
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storm8306(½ð±Ò+5,VIP+0):лл 10-11 18:37
storm8306(½ð±Ò+5,VIP+0):лл 10-11 18:37
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solution samples were prepared by dissolving different amount of calcium chloride into 1wt% surfactant solution. All samples were put in a water bath at 60¡æ for 24h, and then centrifuged at 3000r/min for 1h. The maximum amount of calcium chloride AT which no new phase was separated out was taken as a standard that evaluates the calcium-tolerant stability of surfactant. It (may be) is due to the reason that the formation of a colloid aggregation will at the same time incur the formation of an ¡°electronegative hole¡±[10]. A calcium ion can be buried inside of this ¡°electronegative hole¡± while the distribution of electric charges on the surface of the colloid doesn¡¯t change. Therefore, the formation of the colloid¡¯s inverse structure, which would result in precipitation, was avoided [11]. Moreover, with the length increasing of a hydrophobic chain, the cmc of CnE3SO3 decreased and the number of micelle aggregations increased. Both number and size of ¡°electronegative holes¡± were thus increased. As a consequent, the calcium-tolerant stability was correspondingly enhanced. Adding of strong electrolyte to the solution can accelerate surfactants¡¯ transfer from a water phase to an oil phase, which results in the increase of the diffusion rate of ionic surfactant from solution to interfaces. The electric double layers of diffusion are thus compressed and surfactant molecules are even much densified. Therefore, the emulsion stability is improved. However, with the further increase of electrolyte ( it is weird to use "in salinity" here), the electric double layers of diffusion will be further compressed, which will decrease the wall thickness of the double layers. The possibility of incurring flocculation coalescence will thus become more and more high so that the emulsion will become more and more unstable. seems all done! good luck. will help your proofreading again when having time. [ Last edited by bote on 2009-10-12 at 02:48 ] |
3Â¥2009-10-10 19:45:49
mcphone
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4Â¥2009-10-11 11:48:50
mcphone
ͳæ (СÓÐÃûÆø)
- Ó¦Öú: 2 (Ó×¶ùÔ°)
- ½ð±Ò: 80.6
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- Ìû×Ó: 107
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- ³æºÅ: 441257
- ×¢²á: 2007-10-27
- ÐÔ±ð: GG
- רҵ: »¯Ñ§·´Ó¦¹¤³Ì
5Â¥2009-10-11 11:58:44
storm8306
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6Â¥2009-10-11 19:47:48
storm8306
ľ³æ (ÕýʽдÊÖ)
»á·ÉµÄÓðë
- Ó¦Öú: 18 (СѧÉú)
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- ×¢²á: 2007-08-18
- ÐÔ±ð: GG
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7Â¥2009-10-16 09:24:28















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