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The paper focus on the operation parameters such as temperature,
the weight of active component and the effect of different precursor on the  fractional conversion of NOx

[ Last edited by yyx19840628 on 2009-10-8 at 10:14 ]
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The influence of cobalt loading (10¨C40 wt%Co), cobalt precursor, and promoters (Re,Mn) on the physico-chemical and catalytic properties
of mesoporous Co/SBA-15 catalysts for the Fischer¨CTropsch Synthesis (FTS) reaction (T = 493 K, P = 20 bar, H2/CO = 2) has been
investigated. Catalysts were characterized by N2 and Ar adsorption, X-ray diffraction (XRD), transmission electron microscopy (TEM),
X-ray photoelectron spectroscopy (XPS), and temperature-programmed reduction (TPR). For Co/SBA-15 catalysts prepared from Co(II)
nitrate the dispersion decreased and the extent of cobalt reduction increased with cobalt loading. A maximum CO conversion was found
for the sample with ca. 30 wt% Co loading, though the intrinsic activity of Co remained constant in the range of Co loading studied. More
methane and less C5+ n-paraffins were produced over the less reducible 10 wt% Co loading sample. The addition of ca. 1 wt% Re enhanced
the reducibility of cobalt oxides and increased the catalyst activity, though the intrinsic activity of cobalt sites was not altered. Rhenium
also favored the formation of long-chain n-paraffins (C10+) while decreasing methane selectivity. Promotion of cobalt with ca. 2 wt% Mn
significantly improved cobalt dispersion but decreased its reducibility, producing catalysts that were less active than the unpromoted one.
At similar cobalt loading (ca. 20 wt%), a much better dispersion and a stronger cobalt¨Csupport interaction leading to the formation of lowreducible
cobalt silicates was observed for oxidized samples prepared from acetate and acetylacetonate precursors as compared to that derived
from cobalt(II) nitrate, as evidenced by TEM, XPS, and TPR. The former catalysts were characterized by a low FTS activity and a product
distribution shifted toward the formation of lighter products. Finally, at comparable Co loading Co/SBA-15 catalysts (nitrate precursor) were
about 1.5 times more active per weight of total Co than a Co/SiO2 sample, with only minor differences in product selectivity.

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