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Potential distribution in the evans drop experiment

Caiyun Chen and Florian Mansfeld*

Corrosion and Environmental Effects Laboratory (CEEL) Department of Materials Science and Engineering University of Southern California, Los Angeles, CA 90089-0241, USA

Available online 14 May 1998.

Abstract

The potential distribution adjacent to and under a small drop of NaCl containing phenolphthalein and potassium ferricyanide placed on carbon steel has been determined using a scanning Kelvin probe. Most of the potential drop providing the driving force for dissolution in the center of the drop occurred in thin electrolyte layers adjacent to the drop. Similar results have been obtained in NaCl free of additives and in NaClO4.
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doi:10.1016/S0010-938X(97)83355-0   

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