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Çë°ïæ·ÒëÒÔÏÂÎÄ×Ö£ºTheir impedance was determined by altering the current passing through the cell in a stepwise manner while simultaneously recording the voltage at the cell¡¯s terminals (gal-vanostatic regime) and subsequently subjecting pulses of current and voltage to a Fourier transform¡£ As the setup ensured a voltage compensation at the terminals, the relative error of measurements was reduced to 0.1%.When taking measurements, the capacity of each cell diminished by no greater than 0.05% of the nominal value. To reduce the effect of the passive film at the lithium anode, a ¡°pulse¡± of current (up to 900 s in length,amplitude 50 mA) was passed through the cell before taking each measurement. After each measurement the cell was discharged by short-circuiting it across a 0.3¨C0.32-kohm resistor. The discharge time was ~24 h. The impedance characteristics were monitored after each discharge, without applying the preliminary ¡°pulse.¡±After storing the cells for 80 days, their impedance characteristics were determined once again, but now using the preliminary current pulse. Õâ¶Î»°µÄ´óÒâ¼°ÖØµãÊÇҪȷ¶¨ÊµÑé²½Ö裬ÆäÖÐÓÐÖØµã·ÒëµÄÎÄ×ÖΪ£ºTo reduce the effect of the passive film at the lithium anode, a ¡°pulse¡± of current (up to 900 s in length,amplitude 50 mA) was passed through the cell before taking each measurement. After each measurement the cell was discharged by short-circuiting it across a 0.3¨C0.32-kohm resistor. The discharge time was ~24 h. The impedance characteristics were monitored after each discharge, without applying the preliminary ¡°pulse.¡±After storing the cells for 80 days, their impedance characteristics were determined once again, but now using the preliminary current pulse. ÎÒµÄÀí½âÈçÏ£ºÎª¼õС¶Û»¯Ä¤¶Ôï®Ñô¼«µÄÓ°Ï죬ʹÓÃ900s£¬50mAµÄ´óµçÁ÷Âö³åͨ¹ýµç³Ø£¬ÔÚ²âÁ¿Ç°£¬ÔÚÿ´Î²âÁ¿Ö®ºó£¬Ê¹ÓÃ0.3¨C0.32-kohmµÄµç×è½øÐкã×è·Åµç£¬·Åµçʱ¼ä24Сʱ£¬×迹µÄ²âÁ¿ÔÚÿ´Î·ÅµçÖ®ºó£¬Ã»ÓÐʹÓõçÁ÷Âö³å¡£ÔÚµç³Ø´¢´æ80Ììºó£¬ËüµÄ×è¿¹ÌØÐÔ¾ÍÔٴα»È·¶¨ÏÂÀ´£¬µ«ÊÇÏÖÔÚʹÓõçÁ÷Âö³å¡£ ÎÊÌâÔÚÓÚ:×÷Õß˵£ºÃ¿´Î²âÁ¿Ç°½øÐдóµçÁ÷Âö³å£¬È»ºó²âÁ¿£¬È»ºóÔÙ½øÐжÌ·ºã×è·Åµç£¬·Åµç24Сʱ£¬µ«ÊÇÓÖ˵×迹²âÊÔÔÚÿ´Î·Åµçºó£¬Ã»ÓÐʹÓôóµçÁ÷Âö³å¡£½Ó×Å˵µç³Ø´¢´æ80Ììºó£¬×è¿¹ÌØÐÔÔÙ´ÎÈ·¶¨£¬µ«ÊÇÏÖÔÚʹÓÃÔ¤ÏȵĴóµçÁ÷Âö³å¡£ Õâ¸ö¹ý³ÌºÜÄÑÀí½â¡£ Ï£Íû¸ßÈ˸ø³öÕýÈ·µÄ²½Öè½âÊÍ£¬·Ç³£¸Ðл£¡ |
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