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jasonxmc

金虫 (正式写手)

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虫号: 379143
注册: 2007-05-22
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专业: 电化学

[交流] 【资源】聚合物提高Pt的稳定性

Group里刚刚接受的文章：聚电解质PDDA提高Pt的稳定性。

[RSC]Journal of materials chemistry: Stabilization of platinum nanoparticle electrocatalysts for oxygen reduction using polyelectrolyte

文章链接 http://www.rsc.org/Publishing/Jo ... le.asp?doi=b912104h

Abstract
A long-chain polyelectrolyte, poly(diallyldimethylammonium chloride) (PDDA), has been employed to stabilize platinum nanoparticles for oxygen reduction in polymer electrolyte membrane (PEM) fuel cells. Pt nanoparticles were synthesized by reducing H2PtCl6 with NaBH4 in the presence of PDDA and then deposited on carbon support (PDDA-Pt/C). Transmission electron microscope images showed that Pt nanoparticles of PDDA-Pt/C are uniformly dispersed on carbon support with a mean size of about 2.2 nm (2.1 nm for commercial Etek-Pt/C). PDDA-Pt/C exhibited a higher activity towards oxygen reduction reaction (ORR) than Etek-Pt/C. The durability of PDDA-Pt/C was improved by a factor of 2 as compared with Etek-Pt/C. X-ray photoelectron spectroscopy characterization of PDDA-Pt/C revealed the interaction between Pt nanoparticles and PDDA, which increased Pt oxidation potential and prevented Pt nanoparticles from migrating/agglomerating on or detaching from carbon support. This provides a promising strategy to improve both the durability and activity of electrocatalysts for fuel cells.

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