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[求助] diffusion controlled rate constant

最近投稿,审稿人提出一个关于过渡态和速率问题。Reviewer 2:The discussion of the uranium chemistry has issues with it. There will be no transition state unless the reaction intermediate is quenched and with that much energy being released, that is unlikely. Effectively there is no barrier, and the reaction should be diffusion controlled. What is the diffusion controlled rate constant going to be?请问如何计算扩散控制速率?

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