24小时热门版块排行榜    

北京石油化工学院2026年研究生招生接收调剂公告
查看: 627  |  回复: 0
【悬赏金币】回答本帖问题,作者hdaxiong将赠送您 10 个金币

hdaxiong

新虫 (正式写手)

[求助] 锰卟啉的合成

请教下如何除去锰卟啉合成过程中的四丁基氯化铵??
实验条件如下:Metallation in methanol was accomplished under refluxing conditions, whereas in water it was achieved at room temperature. Routinely, a 1:20 ratio of porphyrin to metal in water at room temperature was applied. The reaction was monitored by UV-visible spectroscopy. Upon completion of metallation (pH brought to ~7), the solution was filtered to remove manganese hydroxo species, and the PF6− salt of manganese complex was precipitated by the addition of a concentrated aqueous solution of NH4PF6. The compound was then dissolved in acetone, the solution was filtered, and a concentrated acetone solution of tetrabutylammonium chloride was added, until the majority of the porphyrin had precipitated in the form of its chloride salt.
紫外表征显示反应成功,但实验过程中有两个问题,第一是加入高浓度的四丁铵氯化铵丙酮溶液后,没有产生沉淀,但刚加入后溶液的颜色就发生很明显的变化,多加颜色不会改变,推测生成了氯盐。第二个是由于锰卟啉不能沉降,尝试用良溶剂和惰性溶剂的方法分离,但发现四丁铵氯化铵能够溶于多数溶液中,很难将其分离。目前没有办法去除掉四丁铵氯化铵,求教。
回复此楼
已阅   回复此楼   关注TA 给TA发消息 送TA红花 TA的回帖
相关版块跳转 我要订阅楼主 hdaxiong 的主题更新
不应助 确定回帖应助 (注意:应助才可能被奖励,但不允许灌水,必须填写15个字符以上)
最具人气热帖推荐 [查看全部] 作者 回/看 最后发表
[考研] 283求调剂 +11 A child 2026-04-04 11/550 2026-04-06 23:05 by chenzhimin
[考研] 287分求调剂 有专利国奖一志愿哈工大085406 +6 白易辰 2026-04-06 7/350 2026-04-06 22:46 by 875465
[考研] 349求调剂 +11 zwjjjjjj 2026-03-31 12/600 2026-04-06 21:27 by zwjjjjjj
[考研] 269电子信息求调剂,可转专业 +5 独酌wl 2026-04-06 5/250 2026-04-06 17:23 by 土木硕士招生
[考研] 0817化学工程与技术求调剂,一志愿中海洋319 +14 lv945 2026-04-04 14/700 2026-04-06 10:20 by 蓝云思雨
[考研] 求调剂,一志愿郑州大学材料与化工专硕,英二数二342分,求老师收留 +19 v12abo 2026-04-02 21/1050 2026-04-06 09:29 by 蓝云思雨
[考研] 化学0703-一志愿211-338分求调剂 +8 vants 2026-04-05 8/400 2026-04-06 06:17 by houyaoxu
[考研] 085600,320分求调剂 +7 大馋小子 2026-04-01 8/400 2026-04-05 21:19 by 学员8dgXkO
[考研] 计算机11408,286分求调剂 +7 木子念晞 2026-04-05 7/350 2026-04-05 19:02 by chy09050039
[考研] 一志愿华中农业大学0710(A)初试329分 求调剂 +4 一名26考研生 2026-04-04 4/200 2026-04-05 10:01 by barlinike
[考研] 292求调剂 +11 2022080213 2026-04-04 13/650 2026-04-04 18:38 by macy2011
[考研] 一志愿武理材料工程302调剂环化或化工 +19 Doleres 2026-03-31 20/1000 2026-04-04 16:44 by 啊俊!
[考研] 一志愿双非085502,267分,过四级求调剂 +3 再忙也要吃饭啊 2026-04-03 3/150 2026-04-04 05:03 by gswylq
[考研] 求调剂 +4 15064154688 2026-04-03 5/250 2026-04-03 15:07 by zrongyan
[考研] 260求调剂 +3 朱芷琳 2026-04-02 3/150 2026-04-03 08:44 by yulian1987
[考研] 279求调剂 +5 傅文秋 2026-04-02 5/250 2026-04-02 18:10 by 笔落锦州
[考研] 270调剂 +7 maxjxbsk 2026-04-02 7/350 2026-04-02 09:50 by yulian1987
[考研] 江苏科技大学招材料研究生 +4 Su032713. 2026-04-01 5/250 2026-04-01 22:03 by cccchenso
[考研] 0710生物学求调剂! +6 叙述文 2026-03-31 6/300 2026-04-01 09:39 by JourneyLucky
[考研] 080500-315分复试调剂 +9 上岸3821 2026-03-31 9/450 2026-03-31 17:29 by 唐沐儿
信息提示
请填处理意见