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【求助】噻唑磷中间体2-噻唑烷酮的性质
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| 各位大虾：请帮忙提供噻唑磷中间体2-噻唑烷酮的性质，最好详细些，谢谢。 |
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yangjianchun
木虫 (著名写手)
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★ ★
小木虫(金币+0.5):给个红包，谢谢回帖交流
mooncakexzj(金币+1,VIP+0):鼓励一下，谢谢参与讨论！ 7-19 20:00
小木虫(金币+0.5):给个红包，谢谢回帖交流
mooncakexzj(金币+1,VIP+0):鼓励一下，谢谢参与讨论！ 7-19 20:00
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又名2一氧代噻唑烷， 国际通用名：2-thiazolidinone 分子式：C3H4NOS； 熔点：49 ℃；沸点：160 C／2 666 Pa；易溶于醇、乙酸乙酯、丙酮、氯仿等有机溶剂，在醚中溶解度较小． 用途：2一噻唑烷酮可直接用作杀菌剂、杀虫剂、植物生长调节剂 ，又是一种重要的农药、医药和染料的中间体 ，如是优良杀线虫剂噻唑磷的重要中间体．此外，随着杂环农药的发展，其在杂环新农药的创制方面也颇有意义． 楼主还可去http://www.sigmaaldrich.com/cata ... &ST=RS&F=PR 查MSDS或者直接查该物质的COA |
2楼2009-07-19 16:50:19
3楼2009-07-19 19:42:04
4楼2009-07-21 11:00:31
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小木虫(金币+0.5):给个红包，谢谢回帖交流
小木虫(金币+0.5):给个红包，谢谢回帖交流
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Registry Number: 154350-29-5 _ Formula: C3 H7 N O2 S CA Index Name: Cyclopropanesulfonamide Experimental Properties Predicted Properties -- Resources -- References: ~154 STN Files: CAPLUS, CA, CASREACT, CHEMCATS, CSCHEM, TOXCENTER, USPAT2, USPATFULL (Additional Information is available through STN International. Contact your information specialist, a local CAS representative, or the CAS Help Desk for Assistance) Database: REGISTRY |
5楼2009-07-21 21:59:09
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Experimental Property Values Registry Number: 154350-29-5 _ Formula: C3 H7 N O2 S CA Index Name: Cyclopropanesulfonamide Property Value Condition Note Carbon-13 NMR See full text (1) CAS Spectrum Carbon-13 NMR See full text (2) CAS Spectrum Carbon-13 NMR See full text (3) CAS Spectrum Carbon-13 NMR See full text (4) CAS Spectrum Melting Point 106-107 癈 Solv: hexane (3) CAS (110-54-3) ethyl acetate (141-78-6) Proton NMR Spectrum See full text (1) CAS Proton NMR Spectrum See full text (2) CAS Proton NMR Spectrum See full text (4) CAS Proton NMR Spectrum See full text (3) CAS Proton NMR Spectrum See full text (5) CAS Proton NMR Spectrum See full text (6) CAS Proton NMR Spectrum See full text (7) CAS Proton NMR Spectrum See full text (8) CAS Notes: (1) Campbell, Jeffrey Allen; WO 2003053349 A2 2003 (2) Wang, Xiangdong Alan; WO 2003099274 A1 2003 (3) Li, Jianqing; Synlett 2006, (5), P725-728 (4) Campbell, Jeffrey Allen; US 2004077551 A1 2004 (5) Ripka, Amy; US 2004048802 A1 2004 (6) McPhee, Fiona; WO 2004094452 A2 2004 (7) Scola, Paul Michael; WO 2005051410 A1 2005 (8) Llinas-Brunet, Montse; WO 2005028501 A1 2005 Database: REGISTRY |
6楼2009-07-21 21:59:43
★ ★ ★
小木虫(金币+0.5):给个红包，谢谢回帖交流
mooncakexzj(金币+2,VIP+0):谢谢应助，编辑到一个或者两个帖子里面就可以了！ 7-21 22:07
小木虫(金币+0.5):给个红包，谢谢回帖交流
mooncakexzj(金币+2,VIP+0):谢谢应助，编辑到一个或者两个帖子里面就可以了！ 7-21 22:07
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Predicted Property Values Registry Number: 154350-29-5 _ Formula: C3 H7 N O2 S CA Index Name: Cyclopropanesulfonamide Property Value Condition Note Bioconcentration 1.0 pH 1 (9) Factor Temp: 25 癈 Bioconcentration 1.0 pH 2 (9) Factor Temp: 25 癈 Bioconcentration 1.0 pH 3 (9) Factor Temp: 25 癈 Bioconcentration 1.0 pH 4 (9) Factor Temp: 25 癈 Bioconcentration 1.0 pH 5 (9) Factor Temp: 25 癈 Bioconcentration 1.0 pH 6 (9) Factor Temp: 25 癈 Bioconcentration 1.0 pH 7 (9) Factor Temp: 25 癈 Bioconcentration 1.0 pH 8 (9) Factor Temp: 25 癈 Bioconcentration 1.0 pH 9 (9) Factor Temp: 25 癈 Bioconcentration 1.0 pH 10 (9) Factor Temp: 25 癈 Boiling Point 263.1?3.0 癈 Press: 760 Torr (9) Density 1.44?.1 g/cm3 Temp: 20 癈 (9) Press: 760 Torr Enthalpy of 50.09?.0 kJ/mol Press: 760 Torr (9) Vaporization Flash Point 112.9?2.6 癈 (9) Freely Rotatable Bonds 1 (9) H Acceptors 3 (9) H Donors 2 (9) H Donor/Acceptor Sum 5 (9) Koc 7.52 pH 1 (9) Temp: 25 癈 Koc 7.52 pH 2 (9) Temp: 25 癈 Koc 7.52 pH 3 (9) Temp: 25 癈 Koc 7.52 pH 4 (9) Temp: 25 癈 Koc 7.52 pH 5 (9) Temp: 25 癈 Koc 7.52 pH 6 (9) Temp: 25 癈 Koc 7.52 pH 7 (9) Temp: 25 癈 Koc 7.50 pH 8 (9) Temp: 25 癈 Koc 7.37 pH 9 (9) Temp: 25 癈 Koc 6.26 pH 10 (9) Temp: 25 癈 logD -0.92 pH 1 (9) Temp: 25 癈 logD -0.92 pH 2 (9) Temp: 25 癈 logD -0.92 pH 3 (9) Temp: 25 癈 logD -0.92 pH 4 (9) Temp: 25 癈 logD -0.92 pH 5 (9) Temp: 25 癈 logD -0.92 pH 6 (9) Temp: 25 癈 logD -0.92 pH 7 (9) Temp: 25 癈 logD -0.92 pH 8 (9) Temp: 25 癈 logD -0.93 pH 9 (9) Temp: 25 癈 logD -1.00 pH 10 (9) Temp: 25 癈 logP -0.920?.598 Temp: 25 癈 (9) Mass Intrinsic Solubility Soluble (96 g/L) Temp: 25 癈 (9) Mass Solubility Soluble (96 g/L) pH 1 (9) Temp: 25 癈 Mass Solubility Soluble (96 g/L) pH 2 (9) Temp: 25 癈 Mass Solubility Soluble (96 g/L) pH 3 (9) Temp: 25 癈 Mass Solubility Soluble (96 g/L) pH 4 (9) Temp: 25 癈 Mass Solubility Soluble (96 g/L) pH 5 (9) Temp: 25 癈 Mass Solubility Soluble (96 g/L) pH 6 (9) Temp: 25 癈 Mass Solubility Soluble (96 g/L) pH 7 (9) Temp: 25 癈 Mass Solubility Soluble (96 g/L) pH 8 (9) Temp: 25 癈 Mass Solubility Soluble (98 g/L) pH 9 (9) Temp: 25 癈 Mass Solubility Very Soluble (120 pH 10 (9) g/L) Temp: 25 癈 Mass Solubility Soluble (96 g/L) Unbuffered (9) Water pH 5.40 Temp: 25 癈 Molar Intrinsic Soluble (0.79 mol/L) Temp: 25 癈 (9) Solubility Molar Solubility Soluble (0.79 mol/L) pH 1 (9) Temp: 25 癈 Molar Solubility Soluble (0.79 mol/L) pH 2 (9) Temp: 25 癈 Molar Solubility Soluble (0.79 mol/L) pH 3 (9) Temp: 25 癈 Molar Solubility Soluble (0.79 mol/L) pH 4 (9) Temp: 25 癈 Molar Solubility Soluble (0.79 mol/L) pH 5 (9) Temp: 25 癈 Molar Solubility Soluble (0.79 mol/L) pH 6 (9) Temp: 25 癈 Molar Solubility Soluble (0.79 mol/L) pH 7 (9) Temp: 25 癈 Molar Solubility Soluble (0.79 mol/L) pH 8 (9) Temp: 25 癈 Molar Solubility Soluble (0.81 mol/L) pH 9 (9) Temp: 25 癈 Molar Solubility Soluble (0.95 mol/L) pH 10 (9) Temp: 25 癈 Molar Solubility Soluble (0.79 mol/L) Unbuffered (9) Water pH 5.40 Temp: 25 癈 Molar Volume 83.7?.0 cm3/mol Temp: 20 癈 (9) Press: 760 Torr Molecular Weight 121.16 (9) pKa 10.69?.20 Most Acidic (9) Temp: 25 癈 pKa -5.38?.70 Most Basic (9) Temp: 25 癈 Polar Surface Area 68.5 A2 (9) Proton NMR Spectrum See spectrum (10) Vapor Pressure 0.0105 Torr Temp: 25 癈 (9) Notes: (9) Calculated using Advanced Chemistry Development (ACD/Labs) Software V8.14 for Solaris (?1994-2009 ACD/Labs) (10) Predicted NMR data calculated using Advanced Chemistry Development, Inc. (ACD/Labs) Software V9.07 (?1994-2009 ACD/Labs) Database: REGISTRY 这些都是在CA上检索到的资料，一部分是它的实验数据，一部分是预测的性质！ 希望对你有帮助 |
7楼2009-07-21 22:01:56
8楼2009-07-22 14:29:04
9楼2009-07-24 20:43:06
ghj-hebust
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10楼2009-12-11 13:54:32