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yanjianfeng

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http://www.namipan.com/d/%e5%b8% ... 172deef8d6052610900

[ Last edited by yanjianfeng on 2009-7-9 at 11:05 ]
2Â¥2009-07-09 11:04:15
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leonumn

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fg2009(½ð±Ò+1,VIP+0): 9-24 10:49
£Â£Ô£Ã£Ô¡¡¡¡¡¡Benzyl thiophene-2-carbodithioate





Reversible addition-fragmentation chain transfer polymerization of styrene using a novel thiophene dithioester as the reversible addition-fragmentation chain transfer agent
Nianchen Zhou 1 2, Lude Lu 1, Jian Zhu 1, Xujie Yang 2, Xin Wang 2, Xiulin Zhu 1 *, Zhengbiao Zhang 1
1School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, China
2Materials Chemistry Laboratory, Nanjing University of Science and Technology, Nanjing 210094, China

email: Xiulin Zhu (xlzhu@suda.edu.cn)

*Correspondence to Xiulin Zhu, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, China

Funded by:
National Nature Science Foundation of China; Grant Number: 20574050
Science and Technology Development Planning of Jiangsu Province; Grant Number: BG2004018
Suzhou City; Grant Number: SG0413, SSZ0419
Nature Science Key Basic Research of Jiangsu Province for Higher Education; Grant Number: 05KJA15008
Specialized Research Fund for the Doctoral Program of Higher Education; Grant Number: 20040285010

Keywords
functionalization of polymers • living polymerization • polystyrene • radical polymerization


Abstract
Benzyl thiophene-2-carbodithioate and 2-methyl-2-(4-methylcyclohex-3-enyl)propyl thiophene-2-carbodithioatewere synthesized. The reversible addition-fragmentation chain transfer polymerizations of styrene with benzyl thiophene-2-carbodithioate and 2-methyl-2-(4-methylcyclohex-3-enyl)propyl thiophene-2-carbodithioate as chain-transfer agents and with 2,2-azobisisobutyronitrile as an initiator were carried out. The polymerization kinetics were investigated. An ab initio calculation method was used to explore the differences between benzyl thiophene-2-carbodithioate and benzyl benzodithioate. The structure of the obtained polymers was characterized with 1H-NMR. Chain-extension experiments of the obtained polymer with styrene were carried out. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007
3Â¥2009-07-09 13:45:59
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leonumn

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School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, China ..... react with BTCT to form the free-radical intermediate. However, the results in Table II ... a structure different from the R group of MPCT. As ...
4Â¥2009-07-09 13:46:48
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