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luckydogzhang

至尊木虫 (著名写手)

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[交流] 求助聚N异丙基丙烯酰胺(PNIPAAm)的玻璃化转变温度

如题,如果能提供可以查找聚合物的玻璃化转变温度的网站更好,谢谢!
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ifand163

金虫 (正式写手)

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luckydogzhang(金币+6,VIP+0):好久不见啊 7-13 08:17
Poly(N-isopropylacrylamide) (variously abbreviated PNIPA, PNIPAAm, PNIPAA or PNIPAm) is a temperature-responsive polymer that was first synthesized in the 1950s.[1]

It forms a three-dimensional hydrogel when crosslinked with N,N’-methylene-bis-acrylamide (MBAm) or N,N’-cystamine-bis-acrylamide (CBAm). When heated in water above 33°C, it undergoes a reversible phase transition from a swollen hydrated state to a shrunken dehydrated state, losing about 90% of its mass. Since PNIPAm expels its liquid contents at a temperature near that of the human body, PNIPAm has been investigated by many researchers for possible applications in controlled drug delivery.[2][3]

呵呵,英文不是很好,是不是说明玻璃化转变温度为33℃啊?从维基百科上找到的,不知道对不对哦^_^

https://en.wikipedia.org/wiki/Poly(N-isopropylacrylamide)

8楼2009-07-12 14:49:27
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