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| Ammonia and hydrogen cyanide are both thermodynamically favored species. Ammonia is favored at low temperatures for the range of oxygen-to-carbon ratios of 0.50–2.50,regardless of the steam-to-carbon ratio. Ammonia production is a strong function of temperature with concentrations approaching zero for temperatures greater than 300 ℃. Hydrogen cyanide is thermodynamically favored under partial oxidation conditions (i.e., steam-to-carbon ratio of 0.00) at high temperatures and low oxygen-tocarbon ratios. The addition of steam inhibits the production of hydrogen cyanide. Increasing the system pressure increases the concentration of ammonia and hydrogen cyanide. |
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Miranda6276
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5楼2009-06-16 16:51:36
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6楼2009-06-16 21:25:07