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[ÇóÖú] XPS±íÕ÷

¸÷λÀÏʦºÃ£¬ÏÖÓÐÎÊÌâÇë½Ì£¬ÎÄÕÂÉó¸åÈËÌáµ½Ò»¸öÎÊÌ⣬ÎÄÏ×Öл·¾³/ԭλXPS¼¼ÊõºÍÎÒÎÄÖÐ×öµÄÕæ¿ÕXPSµÄ²îÒ죬ÈÃ˵Ã÷ÎҵľÖÏÞÐÔ£¬¿ÉÄÜÀí½âµÄ²»ÊǺܵ½Î»£¬¸½ÉÏÒâ¼û£¬»¹ÍûÕâ·½ÃæÀÏʦר¼Ò²»Áߴͽ̡£2) The discussion of the vacuum XPS data fails to acknowledge the significant understanding gained from Song and co-workers on the dynamic nature of the surface under reacting conditions. This work which used environmental XPS in operating conditions informs how the dynamic surface evolves during reactions [5-7]. While this does not invalidate vacuum XPS data, it does show its limitations that the authors should discuss.

5. Du, P.P., et al., Effect of strongly bound copper species in copper-ceria catalyst for preferential oxidation of carbon monoxide. Applied Catalysis a-General, 2016. 518: p. 87-101.
6. Li, L., et al., Water-gas shift reaction over CuO/CeO2 catalysts: Effect of CeO2 supports previously prepared by precipitation with different precipitants. International Journal of Hydrogen Energy, 2011. 36(15): p. 8839-8849.
7. Fox, E.B., et al., In-situ XPS study on the reducibility of Pd-promoted Cu/CeO(2) catalysts for the oxygen-assisted water-gas-shift reaction. Topics in Catalysis, 2008. 49(1-2).

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