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| ÎÒÒѾÕÒµ½Ïà¹Ø½âÊÍÁË£¬ÕâÀïÎÒÌù³öÏà¹Ø¶ÎÂä¡°Surfactants and swelling agents have been used as SDAs, in analogy to mesostructured zeolite synthesis, to get hierarchically micro- and mesoporous MOFs. Triblock copolymers P123 and F127 in ethanol were used to synthesize hierarchically microand mesoporous AlMIL-53 with two types of mesopore diameters.193 The formation of the larger (5.47.6 nm) and the smaller (4.0 nm) pore diameters was attributed to block copolymers and solvent. It was presumed that ethanol reacts with 1,4-benzenedicarboxylic acid under the synthesis conditions and that the resulting organic product acts as a different surfactant creating smaller mesopores. In another study, the surfactant CTAB and the swelling agent TMB were employed to create mesoporous HKUST-1.194 An increase in CTAB/Cu2+ molar ratio enhanced the meosopore diameter from 3.8 to 5.6 nm. A further increase in the mesopore diameter up to 31 nm was achieved by carefully optimizing the TMB/CTAB molar ratio.¡±ÐèÒªµÄÅóÓÑ¿ÉÒÔÏêϸ²Î¿¼Chem. Rev. 2012, 112, 933¨C969¡£ |
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