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??¡¤??????¨®?¡ì???¡Â??????¡Á¨¦?¨°?????¡è¡Á¡Â?¨¨?????????????¨²????¡¤??¨°?????¨²?¨ª?????????¨²???????????¡ã???????????????? ???¨®?? 1?????¨²???¡ì?¨°???????¡ì¡Á¡§???????¨²?? 2???????¡ì?????????¡è?????¨¦???¡è¡Á¡Â?????¡Â?????¡è??????????????????¡Á¡Â?????? 3???????????????¨²?????¨°???????????¨¦?¡ã?????????????????????? ?????¨²?¨ª?????? 1??????6500-8500??/?????¨ª???¡ì?????¡ã?¡è???????????¡§???????????¡è?¨¢?????????????????¡§???¨º??8000???¡ã?¨º???????¡§?????????????¡è¡Á??????????????????¡§?¡ì?? 2??¡À¨ª?????????????????????¨²?¨¢?????????????????¨²?????????¨®?¡ì?????¨¤????¡¤????????????¡ì???????¨¤?¡ì??¡ã¨¹?¡§¡À¡À???¨®?¡ì??????¡À??¡è???¨®?¡ì???????¨®?¡ì???????????¨®?¡ì?????????¨²???¨®?¡ì???????¨®?¡ì?????¡Â???¨®?¡ì????¡Á??¨®?¡ì?????????????????¡§???????¨²?¨°??????https://gs.sustc.edu.cn/zsgailan?? ????¡¤????? ?????¨°??????PDF?????¨º???¨°?¨²??????¡¤?¡À¨ª?¨¦?????¨°???????¡è¡Á¡Â¡Á??¨¢???¨²¡À¨ª¡Á¡Â????????¡¤?????yinq@sustech.edu.cn?¨°chengq@sustech.edu.cn????????¡Á??¡Â?????¡À???? ???¡Â??????¡Á¨¦?¨¦???? ??¡¤??????¨®?¡ì???¡ì?????¡Â??????¡Á¨¦??????2015?¨º????¡¤????????????¨®???????????¡§¡ã¨¹?¡§?????¡À???????????¨²?¨ª???????????¨®???????¨²???????¨²????????¡Á¨¦???¨¦?????¡ã??????¡¤??????¨®?¡ì???¡ã???¡ã?¨´????????¡Á¨¦????HPLC??GC??LC-MS??GC-MS?????¡Á???????¡Â???????¨¨¡À??????¡ì??????400??500?¡Á??????HR-MS??????¡¤?????X-???????¡ì????????X-????¡¤??????????????¡À????????¡¤???¡¤?????????????¡¤??????????????¨®??????¡¤??????¡Â????¡¤??????¨®?¡ì?¨ª?¨¨????????¡¤??????????????¡Â??¡¤??????????¡Â??????¡À?????¡Á¨¦????¡À¨º¡Á????¡ã??????¡Á¨¦???¨´???¡è¡Á¡Â???¡À?¨´?????????¡ã?????¡ì?¨²?????¨¦??¡ã??¨²??¡À¨º¡Á??¡§?¨¨?????¨ª?????¨¦?????¡Â?¨¨¡À??¨´?????????????????????¡è¡Á¡Â???¡À?¨¢?????¡Â???????¡¤??????????¡Á??¨®????¡À??¡è?¡è¡Á¡Â???¡À?????¨ª¡ã????¡ã?????? ???¡ã???¡Â??????¡Á¨¦?¡Â?????????????¨²???¡ì?????????????????????????????????????????¡Á????¡¤????????????¡Á????¡¤???????????????????¡¤??¨°???¡ì?????????¡ã¡¤????¡Â???????????????¡ã?¨²??????????????????¡¤????????¡Á?????????????¨¨????????¡Á¨¦?????????¡Á????????????????¡¤???¡Á????????¨®?¡À?¡Á????????¡ã¡¤????????????¡¤?????¡¤??????????¡ã??¡ã¡¤????¡À????????????????????????????????????¨¹???¨º????¡Á¨¦??PNN pincer??????PNNP???¨¤?????????¨¨??¡¤??????????????????????????????????¨¤??¡Á¡§???????¡ã???????????¨²????????????¡Á???¡Á????¡À?¡Á???????????????????????¡Â???????¡Â????https://chem.sustc.edu.cn/index.php/staff/details/tid/1.html ???¡Â??????¡Á¨¦?¨¹?¨º?¡Â??¡¤?¡À¨ª?????? 1. Tao Yang, Xiaochong Guo, Qin Yin* and Xumu Zhang*, Intramolecular Asymmetric Reductive Amination: Synthesis of Enantioenriched Dibenz[c,e]azepines, Chem. Sci. 2019, 10, 2473-2477. 2. Yazhou Lou, Yutao Hu, Jiaxiang Lu, Fanfu Guan, Gelin Gong, Qin Yin*, Xumu Zhang*, Dynamic Kinetic Asymmetric Reductive Amination: Synthesis of Chiral Primary ??-amino Lactams, Angew. Chem. Int. Ed. 2018, 57, 14193-14197. 3. Gen-Qiang Chen, Bi-Jin Lin, Jia-Ming Huang, Ling-Yu Zhao, Qi-Shu Chen, Shi-Peng Jia, Qin Yin* and Xumu Zhang*; Design and Synthesis of Chiral oxa-Spirocyclic Ligands for Ir-Catalyzed Direct Asymmetric Reduction of Bringmann??s Lactones with Molecular H2. J. Am. Chem. Soc. 2018, 140, 8064¡§C8068. (Highlighted by Synfacts 2018, 14, 1050.) 4. Xuefeng Tan, Shuang Gao, Weijun Zeng, Shan Xin, Qin Yin* and Xumu Zhang*; Asymmetric Synthesis of Chiral Primary Amines by Ruthenium-Catalyzed Direct Reductive Amination of Alkyl Aryl Ketones with Ammonium Salts and Molecular H2. J. Am. Chem. Soc. 2018, 140, 2024¡§C2027. (Highlighted by Synfacts 2018, 14, 0504. and Org. Process Res. Dev. 2018, 22, 421−429.) 5. Qiwei Lang, Guoxian Gu, Yaoti Cheng, Qin Yin* and Xumu Zhang*; Highly Enantioselective Synthesis of Chiral ??-Lactams by Rh-Catalyzed Asymmetric Hydrogenation. ACS Catal. 2018, 8, 4824−4828. (Highlighted by Synfacts 2018, 14, 0832.) 6. Jiao Long, Liyang Shi, Xiong Lia, Hui Lv*, and Xumu Zhang*, Rhodium-Catalyzed Highly Regio- and Enantioselective Hydrogenation of Tetrasubstituted Allenyl Sulfones: An Efficient Access to Chiral Allylic Sulfones. Angew. Chem. Int. Ed. 2018, 57, 13248-13251. 7. Cai You, Xiuxiu Li, Yuhong Yang, Yu-Sheng Yang, Xuefeng Tan, Shuailong Li, Biao Wei, Hui Lv*, Lung-Wa Chung* and Xumu Zhang*, Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation, Nat. Commun. 2018, 9, 1-9. 8. Cai You, Shuailong Li, Xiuxiu Li, Jialing Lan, Yuhong Yang, Lung Wa Chung, Hui Lv,*and Xumu Zhang*, Design and Application of Hybrid Phosphorus Ligands for Enantioselective Rh-Catalyzed Anti-Markovnikov Hydroformylation of Unfunctionalized 1,1-Disubstituted Alkenes. J. Am. Chem. Soc. 2018, 140, 4977¡§C4981. 9. Duanshuai Tian, Chengxi Li, Guoxian Gu, Henian Peng, Xumu Zhang,* and Wenjun Tang*, Stereospecific Nucleophilic Substitution with Arylboronic Acids as Nucleophiles in the Presence of a CONH Group, Angew. Chem. Int. Ed. 2018, 57, 7176-7180. 10. Caiyou Chen, Zhefan Zhang, Shicheng Jin, Xiangru Fan, Mingyu Geng, Yan Zhou, Songwei Wen, Xinrui Wang, Lung Wa Chung,* Xiu-Qin Dong,* and Xumu Zhang*Enzyme-Inspired Chiral Secondary-Phosphine-Oxide Ligand with Dual Noncovalent Interactions for Asymmetric Hydrogenation, Angew. Chem. Int. Ed. 2017, 56, 6808-6812. 11. Caiyou Chen, Shicheng Jin, Zhefan Zhang, Biao Wei, Heng Wang, Kai Zhang, Hui Lv,* Xiu-Qin Dong,*and Xumu Zhang*, Rhodium/Yanphos-Catalyzed Asymmetric Interrupted Intramolecular Hydroaminomethylation of trans-1,2-Disubstituted Alkenes, J. Am. Chem. Soc. 2016, 138, 9017−9020. 12. Cai You, Biao Wei, Xiuxiu Li, Yusheng Yang, Yue Liu, Hui Lv,* and Xumu Zhang*, Rhodium-Catalyzed Desymmetrization by Hydroformylation of Cyclopentenes: Synthesis of Chiral Carbocyclic Nucleosides, Angew. Chem. Int. Ed. 2016, 55, 6511¡§C6514. [ ??¡Á?¡ã??¨¦?? ???? ] |
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