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[交流]
【求助】CaO与SO2反应的平衡常数
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CaO、Ca(OH)2与SO2反应的平衡常数，温度从15℃到200℃， 如果能有反应物的相关参数就更好了。 |
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yytsnake
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Ca(OH)2 + SO2(g) = CaSO3 +H2O(l) T deltaH deltaS deltaG K Log(K) C kcal cal/K kcal 0.000 -39.080 -39.154 -28.385 5.164E+022 22.713 10.000 -38.982 -38.802 -27.995 4.073E+021 21.610 20.000 -38.886 -38.470 -27.609 3.844E+020 20.585 30.000 -38.793 -38.156 -27.226 4.261E+019 19.629 40.000 -38.701 -37.859 -26.846 5.462E+018 18.737 50.000 -38.612 -37.577 -26.469 7.988E+017 17.902 60.000 -38.524 -37.309 -26.094 1.317E+017 17.119 70.000 -38.437 -37.054 -25.722 2.420E+016 16.384 80.000 -38.353 -36.811 -25.353 4.912E+015 15.691 90.000 -38.269 -36.578 -24.986 1.092E+015 15.038 100.000 -38.187 -36.354 -24.621 2.641E+014 14.422 110.000 -38.106 -36.139 -24.259 6.895E+013 13.839 120.000 -38.025 -35.931 -23.899 1.933E+013 13.286 130.000 -37.945 -35.729 -23.540 5.786E+012 12.762 140.000 -37.865 -35.534 -23.184 1.841E+012 12.265 150.000 -37.785 -35.343 -22.830 6.196E+011 11.792 160.000 -37.705 -35.157 -22.477 2.198E+011 11.342 170.000 -37.625 -34.973 -22.127 8.187E+010 10.913 180.000 -37.544 -34.793 -21.778 3.192E+010 10.504 190.000 -37.463 -34.615 -21.431 1.299E+010 10.113 200.000 -37.380 -34.438 -21.085 5.498E+009 9.740 Formula FM Conc. Amount Amount Volume g/mol wt-% mol g l or ml Ca(OH)2 74.095 53.632 1.000 74.095 33.078 ml SO2(g) 64.059 46.368 1.000 64.059 22.414 l g/mol wt-% mol g l or ml CaSO3 120.138 86.960 1.000 120.138 0.000 ml H2O(l) 18.015 13.040 1.000 18.015 18.069 ml |
3楼2009-05-16 19:35:06
yytsnake
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z86197322(金币+1,VIP+0):相当详尽啊！ 5-16 21:12
z86197322(金币+1,VIP+0):相当详尽啊！ 5-16 21:12
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CaO + SO2(g) = CaSO3 T deltaH deltaS deltaG K Log(K) C kcal cal/K kcal 0.000 -54.471 -44.413 -42.339 7.565E+033 33.879 10.000 -54.446 -44.323 -41.896 2.187E+032 32.340 20.000 -54.422 -44.241 -41.453 8.063E+030 30.906 30.000 -54.399 -44.166 -41.011 3.701E+029 29.568 40.000 -54.379 -44.098 -40.569 2.070E+028 28.316 50.000 -54.359 -44.036 -40.129 1.386E+027 27.142 60.000 -54.341 -43.980 -39.689 1.092E+026 26.038 70.000 -54.323 -43.928 -39.249 9.990E+024 25.000 80.000 -54.307 -43.881 -38.810 1.047E+024 24.020 90.000 -54.291 -43.836 -38.371 1.243E+023 23.095 100.000 -54.275 -43.795 -37.933 1.656E+022 22.219 110.000 -54.261 -43.757 -37.496 2.451E+021 21.389 120.000 -54.247 -43.720 -37.058 4.001E+020 20.602 130.000 -54.233 -43.686 -36.621 7.148E+019 19.854 140.000 -54.220 -43.653 -36.184 1.389E+019 19.143 150.000 -54.207 -43.622 -35.748 2.916E+018 18.465 160.000 -54.194 -43.592 -35.312 6.584E+017 17.818 170.000 -54.181 -43.563 -34.876 1.590E+017 17.201 180.000 -54.169 -43.535 -34.441 4.091E+016 16.612 190.000 -54.156 -43.508 -34.006 1.116E+016 16.048 200.000 -54.144 -43.482 -33.571 3.219E+015 15.508 Formula FM Conc. Amount Amount Volume g/mol wt-% mol g l or ml CaO 56.079 46.679 1.000 56.079 16.790 ml SO2(g) 64.059 53.321 1.000 64.059 22.414 l g/mol wt-% mol g l or ml CaSO3 120.138 100.000 1.000 120.138 0.000 ml |
2楼2009-05-16 19:33:46
5