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[求助]
回稿，计算结合常数（非B-H方程）
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今日求助，回稿里有一个问题是让我用非benesi-Hildebrand方程求结合常数，原文如下： Authors applied linear regression Benesi-Hildebrand method to determine association constant Kass. However, this method is not valid for high Ka values (this method correctly describes only soft complex binding; up to K = 5000 mol-1 dm3). Therefore, they should use rather a non-linear regression approach for more precise association constant determination (Chem. Soc. Rev. 2011, 40, 1305-1323). This approach is not difficult with modern computer technology and there is no real excuse for using old-fashion linear transformations anymore (as perfectly summarized by Pall Thordarson in Chem. Soc. Rev. 2011, 40, 1305-1323). 文献我也看了，但是完全看不懂的，不知道吧里有高手会算这个嘛？（文献同时附上） |
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2019-02-12 22:08:31, 2.4 M
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