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Active phases and reaction performance of Mo improved Ni/Al2O3 catalysts for thioetherification
Fuel
Volume 236, 15 January 2019, Pages 525-534
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paperhunter: 楼主要求 2018-12-09 14:52:56
shen_zhibing(paperhunter代发): 金币+10, 楼主要求 2018-12-09 14:53:28
Active phases and reaction performance of Mo improved Ni/Al2O3 catalysts for thioetherification
作者:Shen, ZB (Shen, Zhibing)[ 1 ] ; Ke, M (Ke, Ming)[ 2 ] ; Lan, L (Lan, Ling)[ 3 ] ; He, P (He, Peng)[ 4 ] ; Liang, SR (Liang, Shengrong)[ 1 ] ; Zhang, JT (Zhang, Juntao)[ 1 ] ; Song, H (Song, Hua)[ 4 ]
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FUEL
卷: 236  页: 525-534
DOI: 10.1016/j.fuel.2018.09.045
出版年: JAN 15 2019
文献类型:Article
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摘要
Mo improved Ni/Al2O3 catalysts were prepared and characterized, which demonstrated good catalytic performance for thioetherification process of FCC gasoline. The physico-chemical properties of the Ni/Al2O3 catalysts with different amounts of Mo were characterized by physical techniques and were correlated with their catalytic performance. Experimental results showed that bimetal (Mo and Ni) based catalysts displayed superior catalytic performance than mono-metal (Ni) based catalysts. Addition of Mo to Ni catalysts could inhibit the formation of NiAl2O4 crystallites and facilitate the formation of active precursor NiMoO4, contributing to the formation of more active sites during the presulfidation process. The micro-morphology of active species was restructured and the needle-stacks of Ni-Mo-S were observed on the Mo improved catalysts. These structures and properties had important influence on the thioetherification. By optimizing the Mo/Ni atomic ratio, the catalysts with a Mo/Ni atomic ratio of 0.3 had suitable micro-morphologies and properties, exhibiting the best catalytic performance and selectivity for thioetherification.
关键词
作者关键词:Thioetherification; FCC gasoline; Mo improved Ni/Al2O3 catalysts; Active structure; Ni-Mo-S phase
KeyWords Plus:X-RAY PHOTOELECTRON; HYDRODESULFURIZATION ACTIVITY; NI-MO/GAMMA-AL2O3 CATALYSTS; NI/GAMMA-AL2O3 CATALYSTS; ALUMINA CATALYSTS; NI; HYDROGENATION; CO2; SPECTROSCOPY; TEMPERATURE
作者信息
通讯作者地址: Ke, M (通讯作者)
显示更多        Univ Petr, Coll Sci, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China.
通讯作者地址: Song, H (通讯作者)
显示更多        Univ Calgary, Dept Chem & Petr Engn, Calgary, AB T2N 1N4, Canada.
地址:
显示更多        [ 1 ] Xian Shiyou Univ, Sch Chem & Chem Engn, Xian 710065, Shaanxi, Peoples R China
显示更多        [ 2 ] Univ Petr, Coll Sci, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
显示更多        [ 3 ] PetroChina Petrochem Res Inst, Beijing 102206, Peoples R China
显示更多        [ 4 ] Univ Calgary, Dept Chem & Petr Engn, Calgary, AB T2N 1N4, Canada
电子邮件地址:keming@cup.edu.cn; sonh@ucalgary.ca
基金资助致谢
基金资助机构        授权号
PetroChina Innovation Foundation, China        
2107D-5007-0401
State Key Laboratory of Heavy Oil Processing, China University of Petroleum, China          
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出版商
ELSEVIER SCI LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND
期刊信息
Impact Factor (影响因子): Journal Citation Reports
类别 / 分类
研究方向:Energy & Fuels; Engineering
Web of Science 类别:Energy & Fuels; Engineering, Chemical
文献信息
语言:English
入藏号: WOS:000447799400049
ISSN: 0016-2361
eISSN: 1873-7153
其他信息
IDS 号: GX5OS
Web of Science 核心合集中的 "引用的参考文献": 53
Web of Science 核心合集中的 "被引频次": 0
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