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Where are different electron structure between Eu2+ to Eu3+ exists: the Eu2+ ion has a paramagnetic property (4f7, S = 7/2, L = 0, J = 7/2), while the Eu3+ ion does not have it (4f6, S = 3, L = 3, J = 0) [1-2]. Since ESR can be seen that whether there exist or concentrate Eu2+ paramagnetic ions, so that ESR spectra was used to observe the Eu2+ ion concentration of before and after heat treated process. As shown in Figure S2, the ESR spectra shows that Eu2+ concentration increases due to reduction effect by remanentd low valance of Al elements during heat treated at air atmosphere. It has proved that Eu2+ PL intensity enhanced with heating caused by volume concentration of Eu2+ increased in glass phase.

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³¬¼¶ÀÏ¿ì: ½ð±Ò+100, ·­ÒëEPI+1, ¡ï¡ï¡ïºÜÓаïÖú 2018-04-20 18:58:57
Differences of electron structures between Eu2+ to Eu3+ exist: the Eu2+ ion has a paramagnetic property (4f7, S = 7/2, L = 0, J = 7/2), while the Eu3+ ion does not (4f6, S = 3, L = 3, J = 0) [1-2]. Since ESR can be seen that whether there exist or concentrate Eu2+ paramagnetic ions, ESR spectra were used to observe the Eu2+ ion concentration of before and after heat treated process. As shown in Figure S2, the ESR spectra show that Eu2+ concentration increases due to the reduction effect by remanent low valance of Al elements during heat treated at air atmosphere. It has proved that Eu2+ PL intensity enhanced with heating caused by volume concentration of Eu2+ increased in glass phase.
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