24小时热门版块排行榜

返回列表

【奖励】本帖被评价6次，作者lihai0910增加金币 6 个

当前主题已经存档。

当前只显示满足指定条件的回帖，点击这里查看本话题的所有回帖

lihai0910

至尊木虫 (著名写手)

应助: 22 (小学生)
金币: 26549.3
帖子: 2327
在线: 110小时
虫号: 226499

[资源] 【SSSC-79】Catalysis: An Integrated Approach to Homogenous,

Heterogenous
Catalysis: An Integrated Approach to Homogenous, Heterogenous and Industrial Catalysis (Studies in Surface Science and Catalysis)
By Jacob A. Moulijn, Piet W. N. M. Van Leeuwen

Publisher: Elsevier Science Pub Co
Number Of Pages: 485
Publication Date: 1993-09-01
ISBN-10 / ASIN: 044489229X
ISBN-13 / EAN: 9780444892294

Annotation Catalysis is a multidisciplinary activity which is reflected in this book. The editors have chosen a novel combination of basic disciplines - homogeneous catalysis by metal complexes is treated jointly with heterogeneous catalysis with metallic and non-metallic solids. The main theme of the book is the molecular approach to industrial catalysis.
In the introductory section Chapter 1 presents a brief survey of the history of industrial heterogeneous and homogeneous catalysis. Subsequently, a selection of current industrial catalytic processes is described (Chapter 2). A broad spectrum of important catalytic applications is presented, including the basic chemistry, some engineering aspects, feedstock sources and product utilisation. In Chapter 3, kinetic principles are treated.
The section on fundamental catalysis begins with a description of the bonding in complexes and to surfaces (Chapter 4). The elementary steps on complexes and surfaces are described. The chapter on heterogeneous catalysis (5) deals with the mechanistic aspects of three groups of important reactions: syn-gas conversion, hydrogenation, and oxidation. The main principles of metal and metal oxide catalysis are presented. Likewise, the chapter on homogeneous catalysis (6) concentrates on three reactions representing examples from three areas: carbonylation, polymerization, and asymmetric catalysis. Identification by in situ techniques has been included. Many constraints to the industrial use of a catalyst have a macroscopic origin. In applied catalysis it is shown how catalytic reaction engineering deals with such macroscopic considerations in heterogeneous as well as homogeneouscatalysis (Chapter 7). The transport and kinetic phenomena in both model reactors and industrial reactors are outlined.
The section on catalyst preparation (Chapters 8 and 9) is concerned with the preparation of catalyst supports, zeolites, and supported catalysts, with an emphasis on general principles and mechanistic aspects. For the supported catalysts the relation between the preparative method and the surface chemistry of the support is highlighted. The molecular approach is maintained throughout. The first chapter (10) in the section on catalyst characterization summarizes the most common spectroscopic techniques used for the characterisation of heterogeneous catalysts such as XPS, Auger, EXAFS, etc. Temperature programmed techniques, which have found widespread application in heterogeneous catalysis both in catalyst characterization and simulation of pretreatment procedures, are discussed in Chapter 11. A discussion of texture measurement, theory and application, concludes this section (12). The final chapter (13) gives an outline of current trends in catalysis. Two points of view are adopted: the first one focusses on developments in process engineering. Most often these have their origin in demands by society for better processes. The second point of view draws attention to the autonomous developments in catalysis, which is becoming one of the frontier sciences of physics and chemistry. In this book emphasis is on those reactions catalyzed by heterogeneous and homogeneous catalysts of industrial relevance. The integrative treatment of the subject matter involves many disciplines, consequently, the writing of the book has been a multi-author task. The editors have carefully planned and harmonized the contents of the chapters
BooknewsCatalysis is a multidisciplinary activity, which is reflected in this volume by the choice of a novel combination of basic disciplines--homogeneous catalysis by metal complexes is treated jointly with heterogeneous catalysis with metallic and non-metallic solids. The main theme is the molecular approach to industrial catalysis. The volume contains 13 chapters in six sections: introduction; fundamental catalysis; applied catalysis; catalyst preparation; catalyst characterization; and future trends.
http://img.namipan.com/downfile/56347d752a56f81604e1128e1590380789f5203db7046600/SSSC79.rar

回复此楼