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A mixture of pyrrol and pyrrol covalently attached DNA was electrooxidized, resulting in irreversible immobilization of the oligonucleotides in a polypyrrolic copolymer onto an array of gold microelectrodes. Furthermore, the molecular scale of the biolayer allows rapid diffusion of the electroactive species towards the electrode surface, in comparison with the slower kinetics observed with thin polymeric films or composites. |
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