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| The supposed structure of COF-LZU1 is analogous to that of COF-54, while each edge of the hexagonal ring was substituted by the framework of (N1E,N4E)-N1,N4-dibenzylidenebenzene-1,4-diamine, the geometry of which was optimized with MS DMol3 module..Firstly, we degraded the symmetry of lattice to P1, inserted the optimised monomer in the empty cell, omitted the redundant carbon atoms and all the hydrogen atoms, and promoted the symmetry to P6/m, outputting the crude structure of COF-LZU1¡£ÔÚÎÄÏ×Öп´µ½ÕâÒ»¾ä»°£¬´ÓFirstlyºóÃæÃ»¿´¶®£¬ÕâÀïºÜÃ÷ÏÔÊǴCOFµÄ½á¹¹µÄ£¬Çë½ÌÒ»ÏÂÊÇʲôÒâ˼£¿¾ßÌåÓ¦¸ÃÔõô²Ù×÷¡£ |
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