9楼: Originally posted by 1414170193 at 2017-09-19 11:09:53
表面，随着循环的进行表面NiO层和尖晶石相层逐渐加厚
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10楼: Originally posted by 1414170193 at 2017-09-19 11:13:50
NiO不是电子和锂离子绝缘吗？
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12楼: Originally posted by liliu1989 at 2017-09-19 11:59:09
之前都是这么认为的，但是也有人认为NiO具有一定的电化学活性，还可以有一定的pillar effect。还有文章通过预循环来制造cation mixing(Enhancement on the Cycling Stability of the Layered Ni-Rich Oxide Cathod ...

5楼: Originally posted by liliu1989 at 2017-09-18 18:40:31
有没有相关文献推荐？偏析这个说法最近好像在哪里看到过 但是一晃而过 没有好好看
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15楼: Originally posted by Phys_Xu at 2017-09-19 15:15:43
尺度更“宏观”的

Metal segregation in hierarchically structured cathode materials for high-energy lithium batteries...

13楼: Originally posted by Phys_Xu at 2017-09-19 12:30:16
property和performance的区别
另外，最近deficient-layered structure又被重新拿出来解释layered-to-spinel transformation
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17楼: Originally posted by liliu1989 at 2017-09-19 17:08:09
ceder大神的理论 欢迎讨论

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18楼: Originally posted by Phys_Xu at 2017-09-19 19:10:55
那篇Science？
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