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vincentchu木虫 (著名写手)
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Silicon-Containing Dendritic Polymers (2009新书，联结已更新)
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1 The Role of Silicon in Dendritic Polymer Chemistry ........................... 1 Petar R. Dvornic and Michael J. Owen 2 Polysiloxane and Siloxane-Based Dendrimers ...................................... 21 Aziz Muzafarov and Evgenij Rebrov 3 Carbosilane Dendrimers ......................................................................... 31 Jacques Roovers and Jianfu Ding 4 Polysilane Dendrimers ............................................................................. 75 Masato Nanjo and Akira Sekiguchi 5 Polycarbosilazane and Related Dendrimers and Hyperbranched Polymers ................................................................ 97 David Y. Son 6 Silyl Ether Containing Dendrimers with Cyclic Siloxane Cores ......... 105 Chungkyun Kim 7 Polyhedral Oligomeric Silsesquioxane Dendrimers.............................. 121 Katherine J. Haxton and Russell E. Morris 8 Organometallic Silicon-Containing Dendrimers and Their Electrochemical Applications ................................................ 141 Isabel Cuadrado 9 Carbosilane Dendrimers: Molecular Supports and Containers for Homogeneous Catalysis and Organic Synthesis ........................................................................... 197 Maaike Wander, Robertus J.M. Klein Gebbink, and Gerard van Koten 10 Liquid Crystalline Silicon-Containing Dendrimers with Terminal Mesogenic Groups......................................................... 237 Valery Shibaev and Natalia Boiko 10.1 Introduction ................................................................................... 237 10.2 Peculiarities of the Molecular Structure of LC Silicon-Containing Dendrimers .......................................... 240 10.3 Polyorganosiloxane Dendrimers with Terminal Mesogenic Groups ........................................................................ 241 10.4 Carbosilane LC Dendrimers .......................................................... 246 10.4.1 Synthesis of Carbosilane LC Dendrimers with Different Molecular Architectures .......................... 249 10.4.2 Structural Organization and Phase Behavior of Carbosilane LC Dendrimers ....................................... 252 10.5 Chiral Carbosilane LC Dendrimers with Ferroelectric Properties 262 10.6 Photochromic LC Carbosilane Dendrimers .................................. 269 10.6.1 Phase Behavior and Structure ......................................... 272 10.6.2 Photochemical and Photooptical Properties .................... 274 10.7 Conclusions and Future Outlook ................................................... 279 11 Silicon-Organic Dendrimers ................................................................. 285 Petar R. Dvornic, Michael J. Owen, and Rakesh Sachdeva 11.1 Introduction ................................................................................... 285 11.2 PAMAMOS: PAMAM Dendrimers with Silicon-Containing End-Groups ................................................................................... 287 11.3 PAMAMOS Multi-arm Star Polymers .......................................... 291 11.4 PAMAMOS Networks .................................................................. 294 11.5 PAMAMOS Networks Nanocomplexes and Nanocomposites ..... 298 11.6 Copolymeric PAMAMOS Dendrimers ......................................... 302 11.7 Other Silicon-Organic Dendrimers ............................................... 306 11.7.1 Dendrimers with Silicon in the Core ............................... 306 11.7.2 Dendrimers with Silicon in Their Interiors ..................... 308 11.7.3 Dendrimers (Other than PAMAMOS) with Silicon in the End-Groups ........................................................... 311 12 Hyperbranched Polycarbosilanes via Nucleophilic Substitution Reactions ........................................................................... 315 Leonard Interrante and Qionghua Shen 12.1 Introduction ................................................................................... 315 12.2 Hyperbranched Polycarbosilanes from AB3 Monomers ............... 317 12.2.1 From Chloromethyltrichlorosilane .................................. 317 12.2.2 From 2-Bromo-5-trimethoxysilylthiophene .................... 325 12.2.3 From 2-Bromoethyltrichlorosilane .................................. 327 12.2.4 From 3- or 4-Bromophenyltriethoxysilane ..................... 327 12.2.5 From Other Monomers .................................................... 328 12.3 Hyperbranched Polycarbosilanes from AB2 Monomers ............... 331 12.3.1 From Chloromethylmethyldichlorosilane ....................... 331 12.3.2 From ClCH2CH=CHSiMeCl2 and CH2=C(CH2Cl)SiMeCl2............................................ 333 12.3.3 Other Monomers ............................................................. 335 12.4 Hyperbranched Polycarbosilanes from A2B2-Type Monomers ..... 336 12.5 Hyperbranched Co-Polycarbosilanes ............................................ 338 12.5.1 Co-Polycarbosilanes from Phenyltrichlorosilane, Diphenyldichlorosilane and Dibromomethane ............... 338 12.5.2 Copolymer from ClCH2Si(OMe)1.75Cl1.25 and ClCH2SiMeCl2 .......................................................... 340 12.5.3 Copolymer from Cl2CHSiMeCl2 and ClCH2Si(OMe)1.75Cl1.25 ............................................. 341 12.6 Conclusion and Future Outlook .................................................... 342 13 Hyperbranched Polycarbosilanes and Polycarbosiloxanes via Hydrosilylation Polymerization ...................................................... 345 Hanna Schüle and Holger Frey 13.1 Introduction ................................................................................... 345 13.2 Hydrosilylation .............................................................................. 346 13.3 Synthesis and Characterization of Silicon-Containing Hyperbranched Polymers .............................................................. 349 13.4 Polycarbosilanes ............................................................................ 351 13.4.1 General Synthetic Strategy .............................................. 351 13.4.2 Functionalization ............................................................. 357 13.4.3 Block Copolymers ........................................................... 361 13.5 Polycarbosiloxanes ........................................................................ 363 13.5.1 General Synthetic Strategy .............................................. 363 13.5.2 Polymer Modification and Application ........................... 367 13.6 Polyalkoxysilanes .......................................................................... 370 13.7 Polycarbosilazanes ........................................................................ 371 13.8 Summary and Perspectives ............................................................ 372 14 Rearranging Hyperbranched Silyl Ether Polymers ........................... 377 Daniel Graiver 14.1 Introduction ................................................................................... 377 14.2 Monomer Synthesis ....................................................................... 379 14.3 Polymerization Reactions.............................................................. 381 14.4 Rearrangement Reactions.............................................................. 384 14.5 Possible Applications .................................................................... 386 15 Cyclization Issues in Silicon-Containing Hyperbranched Polymers...................................................................... 391 David Y. Son 15.1 Introduction ................................................................................... 391 15.2 Intramolecular Cyclization of the Monomer ................................. 392 15.3 Intramolecular Cyclization of Oligomers...................................... 393 15.4 Controlling Cyclization ................................................................. 396 15.4.1 Controlling Monomer Cyclization .................................. 396 15.4.2 Controlling Cyclization of Oligomers ............................. 398 15.5 Concluding Remarks ..................................................................... 399 16 Hyperbranched Silicon-Containing Polymers via Bimolecular Non-linear Polymerization ........................................ 401 Petar R. Dvornic and Dale J. Meier 16.1 Introduction ................................................................................... 401 16.2 Historical Development of Bimolecular Non-linear Polymerization ............................................................ 402 16.3 Theory of Ax + By Bimolecular Non-linear Polymerization ......... 404 16.4 Bimolecular Non-linear Polymerization by Hydrosilylation ........ 407 16.4.1 Hyperbranched Polycarbosilanes and Polycarbosiloxanes ................................................... 408 16.4.2 Hyperbranched Polymer Networks ................................. 408 16.4.3 Perfluorinated Hyperbranched Polycarbosiloxanes ........ 411 16.4.4 Hyperbranched Polycarbosiloxanes with Latent Functionalities ................................................................. 412 16.5 Bimolecular Non-linear Polymerization by Nucleophilic Substitution Reactions ................................................................... 413 16.5.1 Hyperbranched Silarylenesiloxanes ................................ 413 16.5.2 Hyperbranched Polysiloxanes ......................................... 414 16.6 Siliconized Hyperbranched Polymers by BMNLP ....................... 415 16.7 Conclusions and Future Outlook ................................................... 417 已经更新了： http://www.namipan.com/d/Silicon ... 2837a6b545e95ff3702 [ Last edited by vincentchu on 2009-6-17 at 01:11 ] |
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