|
|
¡ï ¡ï Сľ³æ(½ð±Ò+0.5):¸ø¸öºì°ü£¬Ð»Ð»»ØÌû½»Á÷ ^_^@^_^(½ð±Ò+1,VIP+0):¼ÌÐø½±Àø£º£© 6-15 11:27
Inorganic Syntheses, vol 34ÖÐÓÐÁ½´¦½²µ½ÁË£¬¿ÉÒÔ¿´¿´
Ru3(CO)12 is an orange air-stable crystalline solid, soluble in a wide variety of
organic solvents, insoluble in water, and volatile.5¨C8 Its IR spectrum, in hexane,
shows CO bands at 2061 (vs), 2031 (s), and 2011 (m) cm1. No band assignable
to a bridging carbonyl ligand is observed.
5. (a) J. L. Dawes and I. D. Holmes, Inorg. Nucl. Chem. Lett. 7, 847 (1971); (b) A. Mantovani and S.
Cenini, Inorg. Synth. 16, 47 (1976).
6. (a) B. R. James and G. L. Rempel, Chem. Indust. 1036 (1971); (b) B. R. James, G. L. Rempel, and
W. K. Teo, Inorg. Synth. 16, 45 (1976).
7. (a) M. I. Bruce and F. G. A. Stone, Chem. Commun. 684 (1966); (b) M. I. Bruce and F. G. A. Stone,
J. Chem. Soc. A 1238 (1967); (c) C. R. Eady, P. F. Jackson, B. F. G. Johnson, J. Lewis, M. C. Malatesta,
M. McPartlin, and W. J. H. Nelson, J. Chem. Soc., Dalton Trans. 383 (1980); (d) M. I. Bruce, J. G.
Matisons, R. C.Wallis, J. M. Patrick, B.W. Skelton, and A. H. White, J. Chem. Soc., Dalton Trans.
2365 (1983); (e) M. I. Bruce, C. M. Jensen, and N. L. Jones, Inorg. Synth. 28, 216 (1987).
8. B. F. G. Johnson and J. Lewis, Inorg. Synth. 13, 92 (1972). |
|