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小木虫(金币+0.5):给个红包，谢谢回帖交流
^_^@^_^(金币+1,VIP+0):继续奖励：） 6-15 11:27
Inorganic Syntheses, vol 34中有两处讲到了，可以看看
Ru3(CO)12 is an orange air-stable crystalline solid, soluble in a wide variety of
organic solvents, insoluble in water, and volatile.5–8 Its IR spectrum, in hexane,
shows CO bands at 2061 (vs), 2031 (s), and 2011 (m) cm1. No band assignable
to a bridging carbonyl ligand is observed.
5. (a) J. L. Dawes and I. D. Holmes, Inorg. Nucl. Chem. Lett. 7, 847 (1971); (b) A. Mantovani and S.
Cenini, Inorg. Synth. 16, 47 (1976).
6. (a) B. R. James and G. L. Rempel, Chem. Indust. 1036 (1971); (b) B. R. James, G. L. Rempel, and
W. K. Teo, Inorg. Synth. 16, 45 (1976).
7. (a) M. I. Bruce and F. G. A. Stone, Chem. Commun. 684 (1966); (b) M. I. Bruce and F. G. A. Stone,
J. Chem. Soc. A 1238 (1967); (c) C. R. Eady, P. F. Jackson, B. F. G. Johnson, J. Lewis, M. C. Malatesta,
M. McPartlin, and W. J. H. Nelson, J. Chem. Soc., Dalton Trans. 383 (1980); (d) M. I. Bruce, J. G.
Matisons, R. C.Wallis, J. M. Patrick, B.W. Skelton, and A. H. White, J. Chem. Soc., Dalton Trans.
2365 (1983); (e) M. I. Bruce, C. M. Jensen, and N. L. Jones, Inorg. Synth. 28, 216 (1987).
8. B. F. G. Johnson and J. Lewis, Inorg. Synth. 13, 92 (1972). |
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