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Similarly, the structure of Ba7(BO3)3GeO4Br is composed of a 3D Ba(1,4, 5)-based framework with tunnels viewed along b axis, in which the BrBa(2, 6)3 chains are located (Fig. 3a). In addition, {[Ba(3)O4(GeO4)]2} double chains and isolated BO3 triangles fill in the framework to form its 3D network structure (Fig. 3b and c). The {[Ba(3)O4(GeO4)]2} double chains are built of isolated GeO4 tetrahedra and Ba(3)O10 polyhedra.
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