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MOF大牛Omar M. Yaghi教授最新Science COF综述--3 Mar 2017
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如题，新一期的science Omar M. Yaghi教授聚焦COF，对COF的前世今生，发展 （atom-molecule-1D COF-2D COF-3D COF-waving COF.........）做出了综述，并对其应用做出了展望。。。。。。。 发来与虫友赏析，希望对大家有所帮助。。。。 ABSTRACT; Just over a century ago, Lewis published his seminal work on what became known as the covalent bond, which has since occupied a central role in the theory of making organic molecules. With the advent of covalent organic frameworks (COFs), the chemistry of the covalent bond was extended to two- and three-dimensional frameworks. Here, organic molecules are linked by covalent bonds to yield crystalline, porous COFs from light elements (boron, carbon, nitrogen, oxygen, and silicon) that are characterized by high architectural and chemical robustness. This discovery paved the way for carrying out chemistry on frameworks without losing their porosity or crystallinity, and in turn achieving designed properties in materials. The recent union of the covalent and the mechanical bond in the COF provides the opportunity for making woven structures that incorporate flexibility and dynamics into frameworks. |
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2017-03-03 19:10:53, 2.95 M
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35楼2017-03-07 10:03:00
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