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关于高聚物的动态机械分析
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DYNAMIC mechanical analysis (DMA)-is a thermal analysis technique that measures the properties of materials as they are deformed under periodic stress. Specifically, in DMA a variable sinusoidal stress is applied, and the resultant sinusoidal strain is measured. If the material being evaluated is purely elastic, the phase difference between the stress and strain sine waves is 0° (i.e., they are in phase). If the material is purely viscous, the phase difference is 90°. However, most real-world materials including polymers are viscoelastic and exhibit a phase difference between those extremes. This phase difference, together with the amplitudes of the stress and strain waves, is used to determine a variety of fundamental material parameters, including storage and loss modulus, tan δ, complex and dynamic viscosity, storage and loss compliance, transition temperatures, creep, and stress relaxation, as well as related performance attributes such as rate and degree of cure, sound absorption and impact resistance, and morphology. The diagram in Figure 1 shows the relationship between several of these parameters. |
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- 附件 1 : 关于高聚物的动态机械分析.PDF
2017-03-02 09:54:39, 300.06 K
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