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请高手帮忙分析我的XRD谱图
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合成Beta分子筛是在5.3左右出现一个高峰，请高手帮忙分析一下这是什么峰。 我Beta分子筛合成原料是，TEA,SiO2,NaOH,NaAlO2,H2O等。按文献来的，做了各种配比（好几十个），老是这样，请指教。。。。 附件一还有Beta峰，附件二就基本连Beta峰都没有了。 [ Last edited by terryxiao on 2008-12-8 at 16:55 ] |
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2楼2008-12-09 08:17:05
duyuhai
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terryxiao(金币+2,VIP+0):谢谢您的分析，再帮我分析下，稍后将数据补上
terryxiao(金币+2,VIP+0):谢谢您的分析，再帮我分析下，稍后将数据补上
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你要是能发数据出来就好了，这样的图，分析会比较麻烦。 建议参考国际沸石协会的网站http://www.iza-online.org/ 和他们出版的《Verified Syntheses of Zeolitic Materials 2nd Revised Edition》 http://www.iza-online.org/synthesis/VS_2ndEd_PDF.htm 另外，你看看这张卡片和你的像不像？ PDF#89-1668(Deleted Card): QM=(Unknown); d=Calculated; I=Calculated Silicon Oxide Si O2 Radiation=CuKa1 Lambda=1.54060 Filter= Calibration= d-Cutoff=17.7 I/Ic(RIR)=56.41 Ref= Calculated from ICSD using POWD-12++ Tetragonal - (Unknown), P4/nmm (129) Z=96 mp= Cell=19.4x7.4 Pearson=tP288 (?) Density(c)=3.438 Density(m)=3.56A Mwt=60.08 Vol=2785.06 F(30)=94.3(.0064,50) Ref= Marler, B., Gruenewald-Lueke, A., Gies, H. Zeolites, 15 388 (1995) Strong Line: 13.7/X 9.70/1 6.86/1 4.57/1 6.13/1 4.34/1 3.43/1 3.07/1 3.40/1 2.74/1 FIZ=086549: Structure calculated theoretically. No R value given. At least one TF missing. Coordinates from paper obviously wrong. Decasils, a new order-disorder family of microporous silicas g14 f2 e2 d4 (P4MM) AX2 d(A) I(f) I(v) h k l n^2 2-Theta Theta 1/(2d) 2pi/d 13.7179 100.0 100.0 1 1 0 6.438 3.219 0.0364 0.4580 9.7000 8.9 12.6 2 0 0 9.109 4.555 0.0515 0.6478 6.8589 4.4 8.8 2 2 0 12.896 6.448 0.0729 0.9161 6.1348 2.3 5.1 3 1 0 14.426 7.213 0.0815 1.0242 5.6302 0.1 0.2 2 1 1 15.727 7.863 0.0888 1.1160 4.8500 0.1 0.3 4 0 0 18.277 9.138 0.1031 1.2955 4.5726 3.4 10.2 3 3 0 19.396 9.698 0.1093 1.3741 4.3380 0.9 2.8 4 2 0 20.456 10.228 0.1153 1.4484 4.3380 0.9 2.8 3 2 1 20.456 10.228 0.1153 1.4484 3.9705 0.1 0.3 4 1 1 22.372 11.186 0.1259 1.5825 3.8047 0.1 0.4 5 1 0 23.361 11.681 0.1314 1.6514 3.7000 0.1 0.4 0 0 2 24.032 12.016 0.1351 1.6982 3.6345 0.3 1.1 1 0 2 24.472 12.236 0.1376 1.7288 3.5723 0.1 0.4 1 1 2 24.904 12.452 0.1400 1.7588 3.4295 0.9 3.6 4 4 0 25.959 12.980 0.1458 1.8321 3.4295 0.9 3.6 4 3 1 25.959 12.980 0.1458 1.8321 3.4034 0.6 2.4 2 1 2 26.162 13.081 0.1469 1.8461 3.3271 0.1 0.4 5 3 0 26.773 13.387 0.1503 1.8885 3.2564 0.1 0.4 2 2 2 27.365 13.683 0.1535 1.9295 3.2333 0.1 0.4 6 0 0 27.564 13.782 0.1546 1.9433 3.2333 0.1 0.4 5 2 1 27.564 13.782 0.1546 1.9433 3.2115 0.2 0.9 3 0 2 27.756 13.878 0.1557 1.9565 3.1684 0.1 0.4 3 1 2 28.141 14.071 0.1578 1.9831 3.0674 0.7 3.1 6 2 0 29.087 14.544 0.1630 2.0484 3.0487 0.2 0.9 3 2 2 29.269 14.635 0.1640 2.0609 2.9417 0.1 0.5 4 0 2 30.360 15.180 0.1700 2.1359 2.9289 0.1 0.5 6 1 1 30.496 15.248 0.1707 2.1452 2.9085 0.1 0.5 4 1 2 30.715 15.358 0.1719 2.1603 2.8763 0.1 0.5 3 3 2 31.067 15.533 0.1738 2.1845 2.8151 0.1 0.5 4 2 2 31.760 15.880 0.1776 2.2320 2.8039 0.1 0.5 5 4 1 31.891 15.945 0.1783 2.2409 2.7436 0.4 2.0 7 1 0 32.611 16.305 0.1822 2.2901 2.6903 0.1 0.5 6 4 0 33.275 16.638 0.1859 2.3355 2.6903 0.1 0.5 6 3 1 33.275 16.638 0.1859 2.3355 2.6777 0.1 0.5 5 0 2 33.437 16.718 0.1867 2.3465 2.6525 0.1 0.5 5 1 2 33.763 16.882 0.1885 2.3688 2.5954 0.1 0.5 7 0 1 34.530 17.265 0.1927 2.4209 2.5811 0.1 0.5 5 2 2 34.726 17.363 0.1937 2.4343 2.5725 0.1 0.5 7 1 1 34.847 17.424 0.1944 2.4425 2.5473 0.1 0.5 7 3 0 35.202 17.601 0.1963 2.4666 2.5152 0.1 0.5 4 4 2 35.667 17.833 0.1988 2.4981 2.5072 0.1 0.5 7 2 1 35.785 17.892 0.1994 2.5061 2.4740 0.1 0.6 5 3 2 36.282 18.141 0.2021 2.5397 2.4667 0.1 0.6 0 0 3 36.393 18.196 0.2027 2.5472 2.4470 0.1 0.6 1 0 3 36.696 18.348 0.2043 2.5677 2.4250 0.1 0.6 1 1 3 37.041 18.520 0.2062 2.5910 2.4250 0.1 0.6 8 0 0 37.041 18.520 0.2062 2.5910 2.4157 0.1 0.6 6 1 2 37.188 18.594 0.2070 2.6009 2.4086 0.1 0.6 7 3 1 37.302 18.651 0.2076 2.6086 2.3526 0.2 1.2 8 2 0 38.224 19.112 0.2125 2.6707 2.3526 0.2 1.2 6 5 1 38.224 19.112 0.2125 2.6707 2.3441 0.3 1.8 5 4 2 38.367 19.184 0.2133 2.6804 2.3047 0.1 0.6 3 0 3 39.051 19.525 0.2169 2.7263 2.3047 0.1 0.6 8 0 1 39.051 19.525 0.2169 2.7263 2.2883 0.1 0.6 8 1 1 39.341 19.671 0.2185 2.7458 2.2785 0.2 1.2 6 3 2 39.517 19.759 0.2194 2.7575 2.2552 0.1 0.6 7 5 0 39.944 19.972 0.2217 2.7861 2.2182 0.1 0.6 7 0 2 40.640 20.320 0.2254 2.8326 2.2038 0.1 0.6 7 1 2 40.916 20.458 0.2269 2.8511 2.1986 0.1 0.6 4 0 3 41.016 20.508 0.2274 2.8577 2.1847 0.1 0.6 6 6 1 41.291 20.646 0.2289 2.8760 2.1847 0.1 0.6 4 1 3 41.291 20.646 0.2289 2.8760 2.1759 0.1 0.6 6 4 2 41.465 20.732 0.2298 2.8876 2.1690 0.1 0.6 8 3 1 41.603 20.802 0.2305 2.8968 2.1690 0.1 0.6 8 4 0 41.603 20.802 0.2305 2.8968 2.1623 0.1 0.6 7 2 2 41.737 20.868 0.2312 2.9057 2.1572 0.1 0.6 7 5 1 41.840 20.920 0.2318 2.9126 2.1424 0.1 0.6 9 1 0 42.145 21.072 0.2334 2.9328 2.1424 0.1 0.6 4 2 3 42.145 21.072 0.2334 2.9328 2.0982 0.1 0.7 7 3 2 43.076 21.538 0.2383 2.9946 2.0816 0.1 0.7 8 4 1 43.436 21.718 0.2402 3.0184 2.0816 0.1 0.7 4 3 3 43.436 21.718 0.2402 3.0184 2.0623 0.1 0.7 6 5 2 43.864 21.932 0.2424 3.0467 2.0579 0.1 0.7 9 1 1 43.963 21.982 0.2430 3.0532 2.0172 0.2 1.4 8 1 2 44.897 22.449 0.2479 3.1148 1.9853 0.1 0.7 8 2 2 45.660 22.830 0.2519 3.1649 1.9813 0.1 0.7 8 5 1 45.756 22.878 0.2524 3.1712 1.9813 0.1 0.7 5 3 3 45.756 22.878 0.2524 3.1712 1.9597 0.1 0.7 7 7 0 46.290 23.145 0.2551 3.2062 1.9597 0.1 0.7 6 0 3 46.290 23.145 0.2551 3.2062 1.9512 0.1 0.7 6 1 3 46.504 23.252 0.2563 3.2202 1.9400 0.1 0.7 10 0 0 46.788 23.394 0.2577 3.2388 1.9353 0.1 0.7 8 3 2 46.910 23.455 0.2584 3.2467 1.9129 0.1 0.7 5 4 3 47.492 23.746 0.2614 3.2847 1.9023 0.1 0.7 10 2 0 47.771 23.886 0.2628 3.3029 1.9023 0.1 0.7 9 4 1 47.771 23.886 0.2628 3.3029 1.8843 0.1 0.7 9 5 0 48.258 24.129 0.2654 3.3345 1.8767 0.1 0.7 10 0 1 48.465 24.232 0.2664 3.3479 1.8767 0.1 0.7 6 3 3 48.465 24.232 0.2664 3.3479 1.8625 0.1 0.7 9 0 2 48.858 24.429 0.2685 3.3735 1.8540 0.1 0.7 9 1 2 49.097 24.549 0.2697 3.3890 1.8500 0.1 0.7 0 0 4 49.211 24.605 0.2703 3.3963 1.8417 0.1 0.7 1 0 4 49.449 24.724 0.2715 3.4117 1.8417 0.1 0.7 10 2 1 49.449 24.724 0.2715 3.4117 1.8334 0.1 0.7 1 1 4 49.687 24.843 0.2727 3.4271 1.8334 0.1 0.7 5 5 3 49.687 24.843 0.2727 3.4271 1.8291 0.1 0.7 9 2 2 49.811 24.905 0.2734 3.4351 1.8260 0.1 0.8 9 5 1 49.901 24.950 0.2738 3.4409 1.8172 0.1 0.8 2 0 4 50.159 25.079 0.2751 3.4575 1.8172 0.1 0.8 6 4 3 50.159 25.079 0.2751 3.4575 1.8093 0.1 0.8 2 1 4 50.394 25.197 0.2763 3.4727 1.8093 0.1 0.8 7 2 3 50.394 25.197 0.2763 3.4727 1.8022 0.1 0.8 10 3 1 50.606 25.303 0.2774 3.4863 1.7862 0.1 0.8 2 2 4 51.093 25.547 0.2799 3.5177 1.7712 0.1 0.8 3 1 4 51.556 25.778 0.2823 3.5474 1.7712 0.1 0.8 8 7 1 51.556 25.778 0.2823 3.5474 1.7564 0.1 0.8 11 1 0 52.024 26.012 0.2847 3.5773 1.7495 0.1 0.8 3 2 4 52.245 26.122 0.2858 3.5915 1.7495 0.1 0.8 10 4 1 52.245 26.122 0.2858 3.5915 1.7431 0.1 0.8 9 6 1 52.452 26.226 0.2869 3.6047 1.7387 0.1 0.8 9 4 2 52.593 26.296 0.2876 3.6137 1.7285 0.1 0.8 4 0 4 52.927 26.464 0.2893 3.6350 1.7285 0.1 0.8 8 0 3 52.927 26.464 0.2893 3.6350 1.7225 0.1 0.8 8 1 3 53.128 26.564 0.2903 3.6478 1.7147 0.1 0.8 3 3 4 53.386 26.693 0.2916 3.6642 1.7147 0.1 0.8 8 8 0 53.386 26.693 0.2916 3.6642 1.7114 0.1 0.8 11 1 1 53.497 26.748 0.2921 3.6713 1.7114 0.1 0.8 10 1 2 53.497 26.748 0.2921 3.6713 1.7015 0.1 0.8 11 3 0 53.835 26.918 0.2939 3.6928 1.6918 0.1 0.8 11 2 1 54.168 27.084 0.2955 3.7139 1.6918 0.1 0.8 10 2 2 54.168 27.084 0.2955 3.7139 1.6791 0.1 0.8 9 5 2 54.613 27.306 0.2978 3.7420 1.6791 0.1 0.8 6 6 3 54.613 27.306 0.2978 3.7420 1.6699 0.1 0.8 4 3 4 54.939 27.469 0.2994 3.7626 1.6637 0.1 0.8 10 6 0 55.159 27.580 0.3005 3.7765 1.6637 0.1 0.8 5 1 4 55.159 27.580 0.3005 3.7765 1.6605 0.1 0.8 10 3 2 55.275 27.637 0.3011 3.7838 1.6605 0.1 0.8 11 3 1 55.275 27.637 0.3011 3.7838 1.6457 0.1 0.8 5 2 4 55.817 27.908 0.3038 3.8180 1.6367 0.1 0.8 8 7 2 56.149 28.075 0.3055 3.8389 1.6282 0.1 0.8 4 4 4 56.470 28.235 0.3071 3.8590 1.6282 0.1 0.8 8 4 3 56.470 28.235 0.3071 3.8590 1.6231 0.1 0.8 9 0 3 56.662 28.331 0.3080 3.8710 1.6231 0.1 0.8 10 6 1 56.662 28.331 0.3080 3.8710 1.6169 0.1 0.8 12 0 0 56.902 28.451 0.3092 3.8860 1.6169 0.1 0.8 5 3 4 56.902 28.451 0.3092 3.8860 1.6139 0.1 0.8 9 6 2 57.015 28.508 0.3098 3.8931 1.6056 0.1 0.9 6 0 4 57.339 28.670 0.3114 3.9134 1.6056 0.1 0.9 11 5 0 57.339 28.670 0.3114 3.9134 1.6009 0.1 0.9 6 1 4 57.523 28.761 0.3123 3.9249 1.6009 0.1 0.9 7 6 3 57.523 28.761 0.3123 3.9249 1.5947 0.1 0.9 12 2 0 57.767 28.884 0.3135 3.9401 1.5920 0.1 0.9 11 0 2 57.872 28.936 0.3141 3.9467 1.5842 0.1 0.9 6 2 4 58.187 29.093 0.3156 3.9662 1.5789 0.1 0.9 5 4 4 58.399 29.199 0.3167 3.9794 1.5789 0.1 0.9 12 0 1 58.399 29.199 0.3167 3.9794 1.5742 0.1 0.9 12 1 1 58.591 29.295 0.3176 3.9913 1.5710 0.1 0.9 11 2 2 58.722 29.361 0.3183 3.9995 1.5584 0.1 0.9 12 2 1 59.244 29.622 0.3208 4.0318 1.5584 0.1 0.9 6 3 4 59.244 29.622 0.3208 4.0318 1.5539 0.1 0.9 10 7 1 59.434 29.717 0.3218 4.0435 1.5539 0.1 0.9 8 8 2 59.434 29.717 0.3218 4.0435 1.5459 0.1 0.9 9 7 2 59.773 29.886 0.3234 4.0645 1.5387 0.1 0.9 9 4 3 60.081 30.040 0.3250 4.0835 1.5387 0.1 0.9 7 0 4 60.081 30.040 0.3250 4.0835 1.5339 0.1 0.9 12 4 0 60.289 30.144 0.3260 4.0963 1.5339 0.1 0.9 5 5 4 60.289 30.144 0.3260 4.0963 1.5242 0.2 1.8 9 9 0 60.711 30.355 0.3280 4.1223 1.5242 0.2 1.8 6 4 4 60.711 30.355 0.3280 4.1223 1.5197 0.1 0.9 10 1 3 60.911 30.456 0.3290 4.1345 1.5197 0.1 0.9 7 2 4 60.911 30.456 0.3290 4.1345 1.5149 0.1 0.9 10 8 0 61.124 30.562 0.3301 4.1476 1.5149 0.1 0.9 11 6 1 61.124 30.562 0.3301 4.1476 1.5126 0.1 0.9 11 4 2 61.226 30.613 0.3306 4.1538 1.4969 0.1 0.9 9 5 3 61.940 30.970 0.3340 4.1975 1.4969 0.1 0.9 7 3 4 61.940 30.970 0.3340 4.1975 1.4929 0.1 0.9 9 9 1 62.125 31.062 0.3349 4.2088 1.4879 0.1 0.9 13 1 0 62.355 31.178 0.3360 4.2228 1.4837 0.1 0.9 6 5 4 62.552 31.276 0.3370 4.2348 1.4837 0.1 0.9 10 8 1 62.552 31.276 0.3370 4.2348 1.4814 0.1 0.9 12 0 2 62.659 31.329 0.3375 4.2413 1.4814 0.1 0.9 0 0 5 62.659 31.329 0.3375 4.2413 1.4771 0.1 0.9 1 0 5 62.862 31.431 0.3385 4.2536 1.4771 0.1 0.9 9 8 2 62.862 31.431 0.3385 4.2536 1.4708 0.1 0.9 8 0 4 63.161 31.581 0.3399 4.2718 1.4708 0.1 0.9 1 1 5 63.161 31.581 0.3399 4.2718 1.4666 0.1 0.9 8 1 4 63.363 31.682 0.3409 4.2841 1.4629 0.1 0.9 13 0 1 63.546 31.773 0.3418 4.2951 1.4603 0.1 0.9 2 1 5 63.671 31.836 0.3424 4.3027 1.4603 0.1 0.9 10 7 2 63.671 31.836 0.3424 4.3027 1.4542 0.1 0.9 13 3 0 63.968 31.984 0.3438 4.3206 1.4542 0.1 0.9 8 2 4 63.968 31.984 0.3438 4.3206 [ Last edited by duyuhai on 2008-12-9 at 08:49 ] |
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