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genhunter
ÖÁ×ðľ³æ (ÖøÃûдÊÖ)
- ·ÒëEPI: 387
- Ó¦Öú: 259 (´óѧÉú)
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- É¢½ð: 10
- ºì»¨: 60
- Ìû×Ó: 2484
- ÔÚÏß: 1793Сʱ
- ³æºÅ: 2558361
- ×¢²á: 2013-07-22
- רҵ: Ö×Áö»¯Ñ§Ò©ÎïÖÎÁÆ
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NY_sky: ½ð±Ò+200, ·ÒëEPI+1, ¡ï¡ï¡ï¡ï¡ï×î¼Ñ´ð°¸, ·Ç³£¸ÐлÄãµÄ°ïÖú£¬½ð±Ò·îÉÏ¡£ 2016-11-28 20:23:03
NY_sky: ½ð±Ò+200, ·ÒëEPI+1, ¡ï¡ï¡ï¡ï¡ï×î¼Ñ´ð°¸, ·Ç³£¸ÐлÄãµÄ°ïÖú£¬½ð±Ò·îÉÏ¡£ 2016-11-28 20:23:03
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ÔÎÄ£º´ËÍ⣬AºÍBÁ½¸öÎü¸½ÌåϵÈÜÒºÖÐCu2+º¬Á¿ËæpHµÄ±ä»¯¹ØÏµ£¨Í¼4£©Ò²¼ä½ÓÑéÖ¤ÁËADS¶ÔCr(III)ºÍCr(VI)Îü¸½ÊÇÁ½ÖÖ²»Í¬µÄÎü¸½»úÖÆ¡£AÌåϵÓÉÓÚÑõ»¯»¹Ô·´Ó¦µÄ·¢Éú²úÉúÁËCr(III)£¨Í¼5£©£¬¶øBÌåϵÊÇÒÔÀë×Ó½»»»ÎªÎü¸½»úÀíµÄ£¬Îü¸½ºóÈÜÒºÖÐÊ£ÓàµÄÒÀÈ»ÊÇCr(III)£¨Í¼£¶£©¡£ÔڽϵÍpHʱ£¬AºÍBÁ½¸öÌåϵÓÉÓÚ´óÁ¿ÖÊ×ӵĴæÔÚ£¬Ê¹Îü¸½¼ÁÏà¶ÔÎȶ¨£¬Òò´ËÎü¸½ºó²ÐÒºÖÐCu2+º¬Á¿Ïà¶Ô½ÏµÍ¡£Ëæ×ÅpHÔö´ó£¬AºÍBÁ½¸öÌåϵ²úÉúµÄCr(III)»á¶ÔÎü¸½¼ÁÖÐCu-S¼ü²úÉúÒ»¶¨µÄÆÆ»µ×÷Ó㬹ʶøÎü¸½ºóÈÜÒºÖÐCu2+º¬Á¿ÂÔÓÐÔö¼Ó£¨Í¼£·£©¡£ In addition, the pH-dependent changes of Cu2+ content in two absorption systems also indirectly verified that the mechanisms for ADS absorption for Cr(III) and Cr(IV) is different. The system A generated Cr(III) due to a redox reaction, while ion exchange was the mechanism for the system B, and Cr(III) was still the leftover after absorption (Figure 6). At relatively low pH, both absorbents were relatively stable, due to the presence of a large excess of protons, therefore the Cu2+ content in the processed liquids were relatively low. As the pH is increased, the Cr(III) produced in both systems deteriorated the Cu-S bonds in the absorbents, therefore after absorption the liquid had a slightly elevated Cu2+ content. |

2Â¥2016-11-28 17:12:15
genhunter
ÖÁ×ðľ³æ (ÖøÃûдÊÖ)
- ·ÒëEPI: 387
- Ó¦Öú: 259 (´óѧÉú)
- ½ð±Ò: 9757.4
- É¢½ð: 10
- ºì»¨: 60
- Ìû×Ó: 2484
- ÔÚÏß: 1793Сʱ
- ³æºÅ: 2558361
- ×¢²á: 2013-07-22
- רҵ: Ö×Áö»¯Ñ§Ò©ÎïÖÎÁÆ
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In addition, the pH-dependent changes of Cu2+ contents in two absorption systems also indirectly verified that the mechanisms for absorption by ADS for Cr(III) and Cr(IV) is different. The system A generated Cr(III) due to a redox reaction, while ion exchange was the mechanism for the system B, and Cr(III) was still the leftover after absorption (Figure 6). At relatively low pHs, both absorbents were relatively stable, due to the presence of a large excess of protons, therefore the Cu2+ content in the processed liquids were relatively low. As the pH was increased, the Cr(III) produced in both systems deteriorated the Cu-S bonds in the absorbents, therefore after absorption the liquid had a slightly elevated Cu2+ content. |

3Â¥2016-11-28 17:54:47














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