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Catalytic Test. The direct hydroxylation of benzene was
performed in the liquid phase in a 50 mL round-bottomed flask
equipped with a reflux condenser and a magnetic stirrer. In a typical
procedure, 20 mmol benzene was mixed with 0.1 g catalyst (FeP?MNTs or conventional mesoporous FePO4, synthesized as in ref 5,
possessing the specific surface area of 258 m2/g, and denoted FeP?MPs) in 20 mL acetonitrile. After the mixture was heated to 333 K
under vigorously stirring, 35 mmol H2O2 (30 wt %) were added
within 30 min. Then, the mixture continued to react for 70 min.
After the reaction, the mixture was separated by centrifugation and
analyzed by gas chromatography. Quantitative calculation was
achieved using o-cresol added after reaction as an internal standard.

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