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huxy3321木虫 (小有名气)
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[交流]
求一篇过期文献，有效期至11月30日
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篇名：On the formation of methane and hydrogen during cracking of alkanes Journal of Molecular Catalysis Volume 32, Issue 3, 15 August 1985, Pages 365-375 这篇文章谁有啊，学校图书馆没有全文。要电子版，或者扫描后的版本都可以，全文哦， 谢谢啦 [ Last edited by huxy3321 on 2008-11-15 at 09:47 ] |
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huxy3321
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4楼2008-11-15 10:14:41
steaven163
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huxy3321(金币+1,VIP+0):虽然不是全文，依旧表示感谢
huxy3321(金币+1,VIP+0):虽然不是全文，依旧表示感谢
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Abstract A qualitative explanation of the low dehydrogenation/cracking ratio observed in reactions with long-chain n-alkanes catalyzed by superacids is attempted via calculation of the MINDO/3 reaction profiles for the complete dehydrogenation intermolecular interconversion cracking (D.I.C.) set of unimolecular processes that a protonated n-alkane can undergo. It is shown that the three simplest systems can suitably model all possible D.I.C. surfaces that can be found in a long-chain linear alkane. The importance of the primary protonation site in the distribution of products is discussed. Some experimental results from cracking of n-heptane over a set of acid zeolites are used, together with those of this theoretical study, to show that a recent controversy about the presence of methane and hydrogen as primary or secondary products in saturated alkane cracking catalyzed by zeolites can be settled. 呵呵，只找到摘要 |
2楼2008-11-15 10:01:19
参蛋
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huxy3321(金币+4,VIP+0):正是我要找的，谢谢啦
huxy3321(金币+4,VIP+0):正是我要找的，谢谢啦
5楼2008-11-15 10:19:46
