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The state of indium ions in nitrate solutions:  a Raman spectroscopic study.     Kozhevnikova, G. V.; Keresztury, Gabor.    Dep. Chem.,  Leningrad State Univ.,  Leningrad,  USSR.    Inorganica Chimica Acta  (1985),  98(1),  59-65.  CODEN: ICHAA3  ISSN: 0020-1693.  Journal  written in English.    CAN 103:13748    AN 1985:413748    CAPLUS  

Abstract

Raman measurements were carried out on aq. In nitrate solns. contg. different additives (NaNO3, HNO3 and NaOH), on a cryst. hydrate In(NO3)3.3H2O, and on its melt.  Band envelope fitting in the region of In-O stretching vibrations (350 to 550 cm-1) yielded component bands which were assigned to different types of complexes present in the solns.: (1) 485 cm-1; the totally sym. breathing vibration of In-O(H2) bonds in hexaaquo In cations, [In(H2)6]3+; (2) 406 cm-1; In-O vibrations of a partly hydroxylated aquo complex of In; (3) 465 and 425 cm-1; In-O(H2) vibrations of aquo complexes contg. 1 more nitrate ion in the 1st coordination sphere of In.  Depolarization ratios of the Raman bands in the 1200 to 1550 cm-1 region allowed one to decide whether mono- and bidentate nitrate complexes of In are formed in some of these systems.  

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