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ch4_hcho
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2Â¥2008-11-07 09:39:35
mland
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The state of indium ions in nitrate solutions: a Raman spectroscopic study. Kozhevnikova, G. V.; Keresztury, Gabor. Dep. Chem., Leningrad State Univ., Leningrad, USSR. Inorganica Chimica Acta (1985), 98(1), 59-65. CODEN: ICHAA3 ISSN: 0020-1693. Journal written in English. CAN 103:13748 AN 1985:413748 CAPLUS Abstract Raman measurements were carried out on aq. In nitrate solns. contg. different additives (NaNO3, HNO3 and NaOH), on a cryst. hydrate In(NO3)3.3H2O, and on its melt. Band envelope fitting in the region of In-O stretching vibrations (350 to 550 cm-1) yielded component bands which were assigned to different types of complexes present in the solns.: (1) 485 cm-1; the totally sym. breathing vibration of In-O(H2) bonds in hexaaquo In cations, [In(H2)6]3+; (2) 406 cm-1; In-O vibrations of a partly hydroxylated aquo complex of In; (3) 465 and 425 cm-1; In-O(H2) vibrations of aquo complexes contg. 1 more nitrate ion in the 1st coordination sphere of In. Depolarization ratios of the Raman bands in the 1200 to 1550 cm-1 region allowed one to decide whether mono- and bidentate nitrate complexes of In are formed in some of these systems. ½ö´Ëһƪ£¬´æÔÚ¸ÃÎïÖÊ£¬CA Registry Number: 96240-62-9 |
3Â¥2008-11-07 10:32:47
tingjiangn
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4Â¥2008-11-07 16:58:27
danmong
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5Â¥2008-11-08 12:04:35
tingjiangn
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6Â¥2008-11-08 17:26:15














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