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[资源] Chem. Rev.最新综述：铜和铜基纳米粒子

本综述全面论述了铜和铜基纳米粒子及其在催化方面的应用。制备方面分为铜与氧化铜纳米粒子，碳支撑铜基纳米，金属氧化物、聚合物、二氧化硅及硅、分子筛铜纳米粒子，以及其他铜基纳米粒子。催化铜粒子的有机转换，光催化，电催化，气相催化等应用。
Cu and Cu-Based Nanoparticles: Synthesis and Applications in Catalysis 共90页引文800篇
Manoj B. Gawande,* ,† Anandarup Goswami,†,‡,§ François-Xavier Felpin,∥ Tewodros Asefa,‡,§ Xiaoxi Huang,‡ Rafael Silva,⊥ Xiaoxin Zou,# Radek Zboril,* ,† and Rajender S. Varma* ,†
†Regional Centre of Advanced Technologies and Materials, Faculty of Science, Department of Physical Chemistry, Palacky University, S ̌ lechtitelu ̊ 11, 783 71 Olomouc, Czech Republic
‡Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 610 Taylor Road, Piscataway, New Jersey 08854, United States
§Department of Chemical and Biochemical Engineering, Rutgers, The State University of New Jersey, 98 Brett Road, Piscataway, NewJersey 08854, United States
∥UFR Sciences et Techniques, UMR CNRS 6230, Chimie et Interdisciplinarite ́ : Synthe ̀ se, Analyse, Mode ́ lisation (CEISAM), Universite ́ de Nantes, 2 Rue de la Houssinie ̀ re, BP 92208, Nantes 44322 Cedex 3, France
⊥Department of Chemistry, Maringa ́ State University, Avenida Colombo 5790, CEP 87020-900 Maringa ́ , Parana ́ , Brazil
#State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, International Joint Research Laboratory of Nano-Micro Architecture Chemistry, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, China

ABSTRACT: The applications of copper (Cu) and Cu-based nanoparticles, which are based on the earth-abundant and inexpensive copper metal, have generated a great deal of interest in recent years, especially in the ﬁ eld of catalysis. The possible modi ﬁ cation of the chemical and physical properties of these nanoparticles using di ﬀ erent synthetic strategies and conditions and/or via postsynthetic chemical treatments has been largely responsible for the rapid growth of interest in these nanomaterials and their applications in catalysis. In addition, the design and development of novel support and/or multimetallic systems (e.g., alloys, etc.) has also made signi ﬁ cant contributions to the ﬁ eld. In this comprehensive review, we report di ﬀ erent synthetic approaches to Cu and Cu-based nanoparticles (metallic copper, copper oxides, and hybrid copper nanostructures) and copper nanoparticles immobilized into or supported on various support materials (SiO 2 , magnetic support materials, etc.), along with their applications in catalysis. The synthesis part discusses numerous preparative protocols for Cu and Cu-based nanoparticles, whereas the application sections describe their utility as catalysts, including electrocatalysis, photocatalysis, and gas-phase catalysis. We believe
this critical appraisal will provide necessary background information to further advance the applications of Cu-based nanostructured materials in catalysis.

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