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[求助]
求帮忙翻译一下这一段的意思,主要是配合物准确的名称是什么
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| Recently, a series of cobalt dithiolene complexes [Co(bdt)2 (bdt = benzene-1,2-dithiolate) (1), Co(tdt)2 (tdt = toluene-3,4- dithiolate) (2), Co(Cl2bdt)2 (Cl2bdt = 3,6-dichloro-bdt)(3), and Co(mnt)2 (mnt = maleonitrile-2,3-dithiolate) (4)], depicted in Chart 1, has been shown to evolve hydrogen in 1:1 (v:v) CH3CN:H 2O. The reduction potentials of the [CoL 2 ] − /[CoL 2 ] 2− couple (i.e., the Co III/II reduction potentials) for these catalysts are ordered according to the electron- withdrawing character of the dithiolene substituents: 4 > 3 > 1 > 2, where complex 4 exhibits the least negative reduction potential. |
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