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[×ÊÔ´] Heusler Alloys: Properties, Growth, Applications

Heusler Alloys: Properties, Growth, Applications
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Contents
Part I Theory of Heusler Compounds
1 Theory of Heusler and Full-Heusler Compounds . . . . . . . . . . . . . 3
Iosif Galanakis
1.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
1.2 Semi-Heusler Compounds . . . . . . . . . . . . . . . . . . . . . . . . . . 6
1.2.1 Band Structure of Semi-Heusler Compounds . . . . . . . 6
1.2.2 Origin of the Gap . . . . . . . . . . . . . . . . . . . . . . . . . . 9
1.2.3 Role of sp-Elements . . . . . . . . . . . . . . . . . . . . . . . . 11
1.2.4 Slater-Pauling Behavior . . . . . . . . . . . . . . . . . . . . . . 12
1.3 Full Heusler Compounds . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
1.3.1 Electronic Structure. . . . . . . . . . . . . . . . . . . . . . . . . 14
1.3.2 Origin of the Gap in Full-Heusler Alloys . . . . . . . . . . 16
1.3.3 Slater-Pauling Behavior of the Full-Heusler Alloys . . . 17
1.4 Inverse Full-Heusler Compounds . . . . . . . . . . . . . . . . . . . . . 19
1.5 LiMgPdSn-Type Heusler Compounds . . . . . . . . . . . . . . . . . . 20
1.6 Disordered Quaternary Heusler Alloys . . . . . . . . . . . . . . . . . . 22
1.7 Half-Metallic Antiferromagnets. . . . . . . . . . . . . . . . . . . . . . . 23
1.8 Magnetic Semiconductors . . . . . . . . . . . . . . . . . . . . . . . . . . 24
1.9 Special Topics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
1.9.1 Exchange Constants and Curie Temperature . . . . . . . . 26
1.9.2 Defects and Vacancies. . . . . . . . . . . . . . . . . . . . . . . 27
1.9.3 Surfaces and Interfaces . . . . . . . . . . . . . . . . . . . . . . 28
1.10 Summary and Outlook. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30
2 Basics and Prospectives of Magnetic Heusler Compounds. . . . . . . 37
C. Felser, L. Wollmann, S. Chadov, G.H. Fecher
and S.S.P. Parkin
2.1 Basics and Prospectives of Magnetic Heusler Compounds . . . . 37
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46Heusler Alloys: Properties, Growth, Applications
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