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诗湘子

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拼命三娘

[求助] 请电化学理论大神指点下如何回答审稿人的意见 已有2人参与

论文根据CV曲线解释反应机理,然后欲计算反应质子和电子的比例,根据dEp/dpH = 2.303mRT/nF得出m/n=0.82接近1,说明电子和质子数目相同。
Comment 1:I strongly against authors' explanation that m/n of 0.82 means the same number of protons and electrons are involved. Also I cannot agree with them that slope of 48.2 mV is very close to Nernstian slope of 59 mV. How could this conclusion be made? Although some literatures show the similar results, that does not mean their explanation is correct. That is why I suggest to introduce parameter beta to explain those phenomena. For example, a glass electrode does not show exact 59 mV dependence upon pH. The value is little lower than that. That's why people introduce beta to correct it. I hope this helps authors revise the manuscript.
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胡琪

铁杆木虫 (著名写手)

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审稿人说你的那个斜率48.2mv比59还低,一般的都是比59大一些,你要怎么解释这个,还有就是m/n接近1说明m=n这个审稿人也强烈不赞同。
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2楼2016-04-04 00:27:23
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小毛球

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审稿人虽然言辞有点激烈但是建议还是很中肯的
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3楼2016-04-05 09:00:29
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