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°æ±¾£ºSECOND EDITION
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1 Some basic concepts 1
1.1 Introduction 1
1.2 Fundamental particles of an atom 1
1.3 Atomic number, mass number and isotopes 2
1.4 Successes in early quantum theory 3
1.5 An introduction to wave mechanics 6
1.6 Atomic orbitals 9
1.7 Many-electron atoms 16
1.8 The periodic table 17
1.9 The aufbau principle 21
1.10 Ionization energies and electron affinities 23
1.11 Bonding models: an introduction 26
1.12 Homonuclear diatomic molecules: valence bond (VB) theory 27
1.13 Homonuclear diatomic molecules: molecular orbital (MO) theory 29
1.14 The octet rule 36
1.15 Electronegativity values 36
1.16 Dipole moments 39
1.17 MO theory: heteronuclear diatomic molecules 41
1.18 Isoelectronic molecules 43
1.19 Molecular shape and the VSEPR model 43
1.20 Molecular shape: geometrical isomerism 48
2 Nuclear properties 53
2.1 Introduction 53
2.2 Nuclear binding energy 53
2.3 Radioactivity 55
2.4 Artificial isotopes 57
2.5 Nuclear fission 58
2.6 Syntheses of transuranium elements 61
2.7 The separation of radioactive isotopes 62
2.8 Nuclear fusion 62
2.9 Applications of isotopes 63
2.10 Sources of 2H and 13C 65
2.11 Multinuclear NMR spectroscopy in inorganic chemistry 67
2.12 Mo¡§ ssbauer spectroscopy in inorganic chemistry 73
3 An introduction to molecular symmetry 79
3.1 Introduction 79
3.2 Symmetry operations and symmetry elements 79
3.3 Successive operations 84
3.4 Point groups 85
3.5 Character tables: an introduction 89
3.6 Why do we need to recognize symmetry elements? 90
3.7 Infrared spectroscopy 90
3.8 Chiral molecules 95
4 Bonding in polyatomic molecules 100
4.1 Introduction 100
4.2 Valence bond theory: hybridization of atomic orbitals 100
4.3 Valence bond theory: multiple bonding in polyatomic molecules 105
4.4 Molecular orbital theory: the ligand group orbital approach and
4.5 Molecular orbital theory applied to the polyatomic molecules BH3,
4.6 Molecular orbital theory: bonding analyses soon become complicated 117
4.7 Molecular orbital theory: learning to use the theory objectively 119
5 Structures and energetics of metallic and ionic solids 131
6 Acids, bases and ions in aqueous solution 162
7 Reduction and oxidation 192
8 Non-aqueous media 214
9 Hydrogen 236
10 Group 1: the alkali metals 257
11 The group 2 metals 275
12 The group 13 elements 293
13 The group 14 elements 338
14 The group 15 elements 385
15 The group 16 elements 432
16 The group 17 elements 468
17 The group 18 elements 492
18 Organometallic compounds of s- and p-block elements 503
19 d-Block chemistry: general considerations 535
20 d-Block chemistry: coordination complexes 555
21 d-Block metal chemistry: the first row metals 593
22 d-Block metal chemistry: the second and third row metals 645
23 Organometallic compounds of d-block elements 700
24 The f-block metals: lanthanoids and actinoids 741
25 d-Block metal complexes: reaction mechanisms 764
26 Homogeneous and heterogeneous catalysis 786
27 Some aspects of solid state chemistry 813
28 The trace metals of life 830
Answers to non-descriptive problems 8

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