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1. ¶àÌúÐÔÄÉÃ׸´ºÏ²ÄÁϽçÃæÖеĴŵçñîºÏЧӦ
Magnetoelectric coupling across the interface of multiferroic nanocomposites
Xiefei Yao, Jing Ma, Yuanhua Lin, Ce-wen Nan, Jinxing Zhang
SCIENCE CHINA Materials, 2015, 58(2): 143-155 | doi:10.1007/s40843-015-0024-7

Abstract  
In recent decades, magnetoelectric effect in multiferroic materials has attracted extensive attention owing to the upcoming demands for new-generation multi-functional magnetoelectronic devices, such as transducer, sensor and so on. This gives people a strong push to explore the multiferroic materials with a reduced dimension and effective coupling between electric and magnetic orderings, especially at room temperature. Due to the weak magnetoelectric coupling strength in sing-phase multiferroic materials, scientists start to design nanocomposites and artificial nanostructures with strong coupling among order parameters (lattice, charge, spin and orbital). In this review, we will introduce recent major progresses of magnetoelectric coupling in multiferroic nanocomposites across their interfaces from the following four aspects: strain effect, charge transfer, magnetic exchange interaction and orbital hybridization, based on their coupling mechanisms. Through a full understanding of the above coupling among these orderings, it is possible to achieve the nanoscale modulation of magnetization (ferroelectric polarization) by external electric (magnetic) field. Apart from the magnetoelectric coupling, those artificially functional nanocomposites provide us a platform to explore and study the emerging physical phenomena so that we can design self-assembled nanostructures to tailor novel functionalities in future applications.
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½ü¼¸Ê®ÄêÀ´, ÈËÃǶÔÓÚÏÂÒ»´ú¶à¹¦ÄܴŵçÆ÷¼þ(ÀýÈç»»ÄÜÆ÷, ´«¸ÐÆ÷µÈ)µÄÐèÇóÔ½À´Ô½¸ß, Òò´ËÎüÒýÁËÖÚ¶à¿ÆÑ§¼Ò̽Ë÷ÓëÑо¿¶àÌúÐÔ²ÄÁϵĴŵçñîºÏЧӦ, ÔÚÊÒÎÂÒÔ¼°µÍάÌõ¼þÏÂѰÇóµçÓë´ÅµÄÇ¿ñîºÏ. ÓÉÓÚµ¥Ïà¶àÌúÐÔ²ÄÁϵĴŵçñîºÏÇ¿¶È·Ç³£Èõ, »òÕßñîºÏζÈÔ¶Ô¶µÍÓÚÊÒÎÂ, ¿ÆÑ§¼ÒÃÇ¿ªÊ¼Éè¼ÆºÍÑо¿¶àÌúÐÔ¸´ºÏ²ÄÁϼ°ÆäÄÉÃ׽ṹ. ±¾×ÛÊö½«´ÓÓ¦Á¦¡¢µçºÉ×ªÒÆ¡¢´Å½»»»×÷ÓÃ, ÒÔ¼°¹ìµÀÔÓ»¯Ëĸö·½Ãæ½éÉܶàÌúÐÔ¸´ºÏ²ÄÁϴŵçЧӦµÄñîºÏ»úÖÆ. ͨ¹ý³ä·ÖÁ˽âÕâЩÐò²ÎÁ¿ÔڴŵçñîºÏЧӦÖеÄ×÷ÓÃ, ÎÒÃÇÄܹ»³É¹¦ÊµÏÖÄÉÃ׳߶ÈÏÂÍâµç³¡(´Å³¡)¶Ô´ÅÐÔÄÜ(ÌúµçÐÔÄÜ)µÄµ÷¿Ø. ´ËÍâ, ÕâЩÈËÔì¶à¹¦ÄÜÄÉÃ׸´ºÏ²ÄÁÏҲΪÉè¼Æ×Ô×é×°ÄÉÃ׽ṹÒÔ¼°½«À´ÊµÏֶ๦ÄÜÆ÷¼þµÄÓ¦ÓÃÌṩÁ˹ãÀ«µÄƽ̨.
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Tunable magnetic and electrical behaviors in perovskite oxides by oxygen octahedral tilting
Ya Gao, Jianjun Wang, Liang Wu, Shanyong Bao, Yang Shen, Yuanhua Lin, Cewen Nan
SCIENCE CHINA Materials, 2015, 58(4): 302-312 | doi:10.1007/s40843-015-0047-0

Abstract  
The oxides with perovskite structure possess abundant physical properties, such as magnetism, dielectricity, photoelectricity, ferroelectricity, etc. The oxygen ions in the perovskite unit cell constitute an octahedral distribution. The deformation or tilting of the special oxygen octahedra structure leads to new performances or properties change. Here, we give a review of the relationship between magnetic and electrical behaviors and oxygen octahedral tilting in several typical perovskite oxides. An understanding of how to tune these properties by controlling the tilting during the sample growth can more effectively guide the design of new structures for high performance and inspiring their potential applications.
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