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[资源] 曹国忠经典著作 Environmental Applications of Nanomaterials

曹国忠老师的英文纳米书籍，第二版。搜索没有重复。纳米材料及纳米表征方面内容非常丰富和权威的书籍。
CONTENTS
Preface to the First Edition v
Preface to the Second Edition ix
Nanoparticle-based Approaches 1
Chapter 1. Nanoparticle Metal Oxides for Chlorocarbon and
Organophosphonate Remediation 3
Olga B. Koper, Shyamala Rajagopalan, Slawomir Winecki
and Kenneth J. Klabunde
1.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
1.2 Environmental Applications of NanoActive Materials . . . . . 9
1.3 Destructive Adsorption of Hazardous Chemicals by
Nanocrystalline Metal Oxides . . . . . . . . . . . . . . . . . . . 10
1.4 Destructive Adsorption of Chemical Warfare Agents (CWAs)
by Nanocrystalline Metal Oxides . . . . . . . . . . . . . . . . . 19
1.5 Safety of NanoActive Materials . . . . . . . . . . . . . . . . . . 21
1.6 Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Chapter 2. Nanoscale Zero-Valent Iron (nZVI) for Site Remediation 25
Daniel W. Elliott, Hsing-Lung Lien and Wei-xian Zhang
2.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
2.2 Overview and ZVI General Process Description . . . . . . . . . 26
2.2.1 Applications of ZVI to environmental remediation . . . 26
2.2.2 ZVI process description: Chemical fundamentals . . . . 28
2.2.3 ZVI process description: Mechanistic aspects . . . . . . 30
2.2.4 Kinetic models of the ZVI process . . . . . . . . . . . . 30
2.3 Overview of Major Methodologies for Synthesizing nZVI . . . 32
2.3.1 Type I nZVI using the chloride method . . . . . . . . . 33
2.3.2 Types II and III nZVI using the sulfate method . . . . 33
2.4 Characterization of nZVI . . . . . . . . . . . . . . . . . . . . . 36
2.5 Summary of nZVI Research and Applications . . . . . . . . . . 38
2.5.1 Laboratory batch studies . . . . . . . . . . . . . . . . . 38
2.5.2 Field testing demonstration . . . . . . . . . . . . . . . 43
2.6 Challenges Ahead . . . . . . . . . . . . . . . . . . . . . . . . . 44
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46
Chapter 3. Synthesis, Characterization, and Properties of Zero-Valent
Iron Nanoparticles 49
Donald R. Baer, Paul G. Tratnyek, You Qiang,
James E. Amonette, John Linehan, Vaishnavi Sarathy,
James T. Nurmi, Chongmin Wang and J. Antony
3.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49
3.2 Synthesis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51
3.2.1 Vapor-phase nanoparticle synthesis . . . . . . . . . . . 52
3.2.2 Solution-phase synthesis . . . . . . . . . . . . . . . . . 56
3.3 Particle Handling and Characterization . . . . . . . . . . . . . 60
3.3.1 Challenges for nanoparticle handling and
characterization . . . . . . . . . . . . . . . . . . . . . . 60
3.3.2 Ex situ examples of iron nanoparticle
characterization . . . . . . . . . . . . . . . . . . . . . . 63
3.4 Methods for Characterizing Reactivity in Solution . . . . . . . 75
3.4.1 Electron paramagnetic resonance (EPR) spectroscopy . 76
3.4.2 Electrochemicalmethods . . . . . . . . . . . . . . . . . 78
3.4.3 Batch and column methods . . . . . . . . . . . . . . . 79
3.5 Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82
Nanostructured Inorganic Materials 87
Chapter 4. Formation of Nanosized Apatite Crystals in Sediment for
Containment and Stabilization of Contaminants 89
Robert C. Moore, Jim Szecsody, Michael J. Truex,
Katheryn B. Helean, Ranko Bontchev and Calvin Ainsworth
4.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89

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2016-03-04 15:36:39, 12.38 M

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