最新一期的Chem. Soc. Rev.杂志刊发了由德国马普研究所Xinliang Feng课题组撰写的题为Nanocomposites and macroscopic materials: assembly of chemically modified graphene sheets的综述,介绍了化学修饰石墨烯(负载、杂化、修饰)的研究进展,对合成和应用做了详细的介绍。文章18页,引文230篇。
Self-assembly of chemically modified graphenes (CMGs), including graphene oxide (GO), reduced graphene oxide (RGO) and their derivatives, has emerged as one of the most appealing strategies to develop unprecedented graphene-based functional materials. With the assistance of various non-covalent forces such as hydrogen bonding, ionic, amphiphilic and p–p interactions, CMGs decorated with multiple functional groups are favorable for assembly with different organic and
inorganic components which can result in hierarchical composites possessing unique structures and functions. In this review, we will summarize the state-of-the-art self-assembly strategies that have been established to construct CMG based nanomaterials, including nanoparticles, nanospheres, nanofibers, nanorods, nanosheets, and macroscopic thin films, fibers and porous networks. The driving forces involved in the self-assembly process will be elucidated in the context. Further, we will also highlight several representative examples of applications
regarding the self-assembled CMG based materials.
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